4.7 Article

Trifluoromethyl functionalized sulfonated polytriazoles from diphenylphosphine oxide-based dialkyne via click polymerization: Effect of high content of phosphorus on the proton exchange membrane properties

期刊

EUROPEAN POLYMER JOURNAL
卷 162, 期 -, 页码 -

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2021.110869

关键词

Phosphine oxide moiety; Click polymerization; Sulfonated copolytriazoles; Proton conductivity; Oxidative stability

资金

  1. Wacker-Metroark Chemicals Pvt. Ltd. [WACKER-IIT Kgp 2020/03]
  2. UGC, New Delhi, India

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A new diphenylphosphine oxide based dialkyne, POALK, was synthesized under mild conditions and used to prepare fluorinated sulfonated polytriazoles via click polymerizations with other comonomers. The resulting sulfonated polymers showed exceptional thermal, mechanical, and thermomechanical stability, along with high proton conductivity. The presence of triarylphosphine oxide units in the polymers contributed to slowing down peroxide radical attacks and facilitating proton transportation through ionic nanochannels.
A new diphenylphosphine oxide based dialkyne, [2,5-bis(prop-2-yn-1-yloxy)phenyl]diphenylphosphine oxide (POALK) has been prepared under mild reaction conditions. Using this POALK monomer, a new-fangled fluorinated sulfonated polytriazoles (PTPPS-70 to -90 and PTPS-100) with a high content of phosphine oxide moieties were prepared via the click polymerizations with other two comonomers [sulfonated diazide (DSAZ) and non-sulfonated phosphorus containing diazide (PFAZ)]. FT-IR and NMR (H-1, C-13, and P-31) spectroscopic techniques were used for the structural elucidations of the synthesized monomer and polymers. The high molecular weight (weight average molecular weight: 59,600-75,800 g mol(-1) and PDI: 1.65-2.20) sulfonated polymers demonstrated exceptional thermal, mechanical and thermomechanical steadiness. The higher content of phosphorus (3.83-4.54%) in the copolymers (IECW: 1.58-2.16 meq g(-1)) has occasioned excellent harmony among the water uptakes (WU), swelling ratios (SR), and proton conductivity (sigma). The coexistence of triarylphosphine oxide units (both in the dialkyne and diazide monomers) in the polymers slowed down the peroxide radical attacks. The observed interconnected ionic nanochannels in the phase segregated morphology in AFM and TEM images of sulfonated polytriazoles (PTPPS-70 to -90 and PTPS-100) facilitate the proton transportation that resulted in high proton conductivity.

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