期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2021, 期 39, 页码 5449-5452出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202101177
关键词
Alkenes; Hydrosiloxane; Hydrosilylation; Nickel; Pincer complex
A new method for the hydrosilylation reaction of alkenes has been developed using 1,1,3,3-tetramethyldisiloxane as a substitute for Me2SiH2, catalyzed by a nickel-pincer complex with a monoanionic O,N,P-tridentate ligand under mild reaction conditions. The reaction proceeds smoothly with high yields and high Markovnikov selectivity for styrene derivatives. The protocol shows a wide substrate scope and compatibility with various functional groups, including secondary hydrosilanes.
We have developed a hydrosilylation reaction of alkenes using 1,1,3,3-tetramethyldisiloxane (TMDS) as a surrogate for Me2SiH2 in the presence of NaOMe, catalyzed by a bench-stable nickel-pincer complex supported by a monoanionic O,N,P-tridentate ligand. The reaction of styrene derivatives proceeds smoothly under mild reaction conditions to provide the hydrosilylated products in high yields with high Markovnikov selectivity. This protocol shows a wide substrate scope and is compatible with a wide range of functional groups. Secondary hydrosilanes are also suitable under the present reaction conditions and furnish the desired products in high yields.
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