期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 2022, 期 7, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.202100986
关键词
Cage compounds; Enantiomeric cages; Heterogeneous catalysis; Palladium; Self-assembly
资金
- SERB-New Delhi (India)
This study presents the facile synthesis of two face-directed tetrahedral organic cages by condensation reaction. These cages are large with intrinsic porous cavities and exhibit high thermal stability. The synthesized cages can be used as solid supports for the synthesis of palladium nanoparticles, which show efficient catalytic activity for selective homocoupling reactions.
Numerous metalla-supramolecular architectures have been designed using coordination-driven self-assembly, while the number of analogous organic architectures is still very limited. In this regard, mainly di-, tri- and a few tetra-aldehydes have been exploited as precursors in combination with appropriate di-/tri-amines to obtain the desired structures with limited complexities. We report here facile synthesis of two face-directed tetrahedral organic cages (TC-R and TC-S) that were formed by [4+12] imine condensation of a new hexa-aldehyde precursor with two enantiomers of 1,2-diaminocyclohexane separately (CA-R and CA-S). The covalent imine cages are very large with an intrinsic porous cavity of similar to 1250 angstrom(3) and the faces of the cages consist of aromatic aldehyde units whereas each corner is occupied by three semi-flexible diamine moieties. Palladium (PdNPs) nanoparticles (3.5 +/- 0.3 nm) were synthesized employing the cage TC-R as a solid support via double-solvent approach. Furthermore, the cage hosted PdNPs [Pd(0)@TC-R-A] exhibited efficient catalytic activity for selective homocoupling of aryl- and hetero-aryl halides with high thermal stability and reusability.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据