期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 2022, 期 12, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.202101067
关键词
Ferrocene; Gold; Homogeneous catalysis; Phosphane ligands; Redox chemistry
资金
- Agencia Estatal de Investigacion (AEI) [PID2019-104379RB C21, PID2020-117455GB I00/AEI/10.13039/501100011033]
- Gobierno de Aragon-Fondo Social Europeo [E07_20R]
This review explores the recent advancements in the combination of the ferrocene structure with gold-mediated catalysis in the field of organometallic chemistry, discussing the application and potential of ferrocene in gold catalysis.
More than half a century after the discovery of the ferrocene structure in 1951, it remains as a suitable building block in many research areas, including catalysis with the development of key chiral catalysts. On the other hand, gold-mediated catalysis has been raised in recent years, allowing the creation of a great variety of C-C bonds and C-heteroatom bonds. In this context, this review covers the recent advances made with the combination of these two iconic figures in the organometallic chemistry field, since the first gold catalyzed reaction using a ferrocene ligand reported in 1986. The combination of the excellent properties and versatility of this metallocene, has allowed the obtainment of a plethora of ligands for metal catalysis, although their use joined to gold catalysis is still scarcely explored.
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