期刊
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
卷 29, 期 13, 页码 18882-18890出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s11356-021-17167-1
关键词
4-Nonylphenol; Ferrate(VI); C-14-labeled 4-nonylphenol; Degradation product; Estrogenic activity
资金
- JSPS KAKENHI [JP 25420554]
- Obayashi Foundation
In this study, the biodegradability of 4-NP and its degradation products in the presence of ferrate(VI) were evaluated. It was found that 4-NP was not completely mineralized and formed degradation products when ferrate(VI) was added. Mass spectra analysis revealed a unique peak at m/z 223 for the degradation products of 4-NP with Fe(VI). Furthermore, the estrogenic activity of 4-NP in aqueous solution was significantly reduced with increasing Fe(VI) concentration.
4-Nonylphenol (4-NP) is an endocrine-disrupting and persistent chemical and is partially degraded in conventional wastewater treatment processes. Ferrate(VI) can be used as an environment-friendly oxidizing agent to mediate 4-NP degradation. Thus, this paper evaluates the biodegradability of 4-NP and its degradation products after the addition of ferrate(VI). The biodegradability was examined using NP labeled with C-14 as a tracer and activated sludge microorganisms as an inoculum. The addition of ferrate(VI) to the 4-NP solution spiked with the tracer resulted in no remarkable decrease in the concentration of C-14, indicating incomplete mineralization of 4-NP and formation of degradation products. The degradation products from 4-NP with Fe(VI) were estimated based on mass spectra, which detected a unique peak at m/z 223 at low intensity. Four hydrogen atoms might have been added to 4-NP by degradation with Fe(VI). In addition, the effect of ferrate(VI) concentration on the estrogenic activity of 4-NP in an aqueous solution was investigated using a yeast bioassay. The results show that estrogenic activity was significantly decreased at a mass ratio of Fe(VI) to 4-NP greater than or equal to 2.5.
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