期刊
ENERGY CONVERSION AND MANAGEMENT
卷 251, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.enconman.2021.114974
关键词
Biojet Fuel; Catalyst; Production pathway; Sustainable Aviation Fuel; Hydroprocessed esters and fatty acids
资金
- Ministry of Science and Technology of the People's Republic of China [BZ2800002]
- Slovenian Research Agency [BI-CN/20-22-022, Z2-1862, P2-0401]
- Chinese Government Scholarship (CSC)
This study reviews technologies and catalysts for producing synthetic jet fuels, as well as the use of biomass resources as feedstock. It discusses the production process and challenges for uncertified biojet fuels.
Sustainable Aviation Fuel (SAF) has become an important measure in the aviation industry's efforts to mitigate carbon emissions and reduce their overall environmental impacts. However, commercial usage is relatively stunted due to a plethora of drawbacks in the production process and economic feasibility of the fuel. In this study, the currently accepted technologies for producing synthetic jet fuels under the American Society for Testing Material (ASTM D7566) standard specification for aviation turbine fuel are reviewed. The emphasis is placed in terms of their reactions, type of catalysts used for the conversion pathways of Fisher-Tropsch (FT), Hydroprocessed Esters and Fatty Acids (HEFA) and Alcohol-to-Jet (ATJ), and the use of biomass resources as feedstock. The advancement in the production process and physicochemical properties of the uncertified biojet fuels are reviewed and discussed. Generally, Co- and Fe-based catalysts are commonly used for the FT process, while bimetallic catalysts consisting of Pt, Pd, Ni and Mo have shown excellent activities and selectivities for the HEFA process. For the ATJ process, zeolites such as HZSM-5, beta and SAPO have shown remarkable ethanol dehydration efficiency, while TiO2 and ferrierite have been studied for the combined iso-butanol dehydration and oligomerisation processes. Fundamental factors influencing the reaction efficiency including the feedstock properties, reaction conditions, catalytic reusability and catalyst supports are discussed. Finally, the key challenges and prospects for biojet fuel commercialisation are addressed.
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