期刊
ELECTROCHIMICA ACTA
卷 398, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2021.139336
关键词
Magnesium-ion battery; Magnesium alloys; Alloy anode; Microstructure
资金
- Marsden Fund Council from Government [UOA1817]
In this study, the electrochemical performance of hypoeutectic Mg-Sn alloy anodes with all-phenyl complex (APC) electrolyte was investigated. The Mg14Sn alloy anode displayed different electrochemical behaviors compared to pure Mg, with lower resistance observed after 30 cycles.
Mg metal has been used as an anode material for Mg-ion rechargeable batteries (MRBs), but the un-desired passivation layer between Mg and electrolyte indeed limits the further development of MRBs. Replacing Mg with Sn and Mg2Sn has been proved to be an alternative for Mg ions storage based on the alloying reaction between Mg and Sn. In the present study, we have investigated the electrochem-ical performance of hypoeutectic Mg-Sn alloy anodes with an all-phenyl complex (APC) electrolyte. The microstructure and electrochemical results indicate that the Mg14Sn alloy anode displays different elec-trochemical behaviors of Mg stripping/plating due to the formation of eutectic (alpha-Mg+ Mg2Sn) phase. Special anodic peaks, different reaction sites and high overpotential are observed in the Mg14Sn alloy anode. Electrochemical impedance spectroscopy (EIS) results show that the anode-electrolyte interface is significantly affected by the addition of Sn. Mg14Sn alloy anode shows much lower resistance than pure Mg after 30 cycles. The results obtained from electron microscopic observations confirm that the formation of nanosized beta-Sn stems from the eutectic phase. (C) 2021 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据