Reasonable design of a V2O5-x/TiO2 active interface structure with high polysulfide adsorption energy for advanced lithium-sulfur batteries

A sulfur composite active material for lithium-sulfur batteries with a highly active interface structure can display excellent electrochemical performances. For this reason, in this paper, we design a type of V2O5-x/TiO2 active interface structure with high polysulfide adsorption energy as a high-performance sulfur-wrapped matrix. Physical property characterization indicates this interface is constructed from circular anatase structure TiO2 and anoxic vanadium oxide structure composed of V4+ and V5+ . After sulfur wrapping, Ti-S and S-S bond structures are produced by chemical and physical adsorption. Density functional theory calculations show that the V2O5-x/TiO2 interface has very high adsorption energy (-5.93 eV) with lithium polysulfide (Li2S6). After sulfur wrapping as a cathode active material, it displays low electrochemical charge transfer resistance (31.89 Omega) and high lithium-ion transfer efficiency (3.50 x 10(-12)). In addition, it has rather high discharge specific capacities of 1466.47, 963.84 and 801.16 mAh.g(-1) at 0.1, 0.2 and 0.5 C, respectively. After 500 cycles, the discharge capacity retention at 0.5 C is up to 76.11% corresponding to 0.048% capacity decay rate per cycle. This is the reason that the V2O5-x/TiO2 active interface has very strong adsorption to polysulfide and can effectively suppress the shuttle effect (Q(low)/Q(high) = 1.44 at 0.2 C). (c) 2021 Elsevier Ltd. All rights reserved.

Automated summary

In this study, a V2O5-x/TiO2 active interface structure with high polysulfide adsorption energy was designed for lithium-sulfur batteries, which exhibited improved electrochemical performances. The interface showed low electrochemical charge transfer resistance and high lithium-ion transfer efficiency. The sulfur-wrapped cathode material displayed high specific capacities and good cycling stability.