期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 133, 期 -, 页码 -出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2021.107160
关键词
Solvate ionic liquid; Electrodeposition; Magnesium; Aluminum-magnesium alloys
资金
- National Natural Science Foundation of China [52074084, 52004062]
An aluminum-containing solvate ionic liquid was used as the electrolyte for magnesium electrodeposition, and coating of Al3Mg2 can be prepared by potentiostatic electrodeposition.
An aluminum-containing solvate ionic liquid, DMI-AlCl3 (1 M)-MgCl2 (0.5 M) was used as the electrolyte for magnesium electrodeposition. The results of Raman spectroscopy and Al-27 nuclear magnetic resonance spectroscopy indicated the existence of aluminum-containing [AlCl4](-) and [AlCl2(DMI)(4)](+) in the DMI-AlCl3 (1 M) system. When 0.5 M MgCl2 was added to DMI-AlCl3, the Mg(II) species was [MgCl(DMI)(n)](+). X-ray diffraction analysis indicated that a coating of Al3Mg2 can be prepared by potentiostatic electrodeposition at 1.45 V (vs. Al) at 323 K on a copper sheet cathode.
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