期刊
DYES AND PIGMENTS
卷 195, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2021.109714
关键词
Naphthalimide; Donor and acceptor; Aggregation mode; C=N isomerization; pH/ion sensing
资金
- Shaoxing university
- National Natural Science Foundation of China [51407134]
- Program for Changjiang Scholars and Innovative Research Team in University
- Testing Foundation of Nanjing University
Novel naphthalimide-based fluorescent molecules have been developed as fluorescence chemosensors with high sensitivity and selectivity towards H+ and Al3+ due to their C=N isomerization-based fluorescence turn-on mechanism. By adjusting the structure and chain length, their photophysical properties can be controlled, leading to strong solid-state fluorescence and excellent thermal stability for potential high-temperature applications.
A series of new type naphthalimide-based fluorescent molecules linking aniline-like groups via a coupling chain with -C=N- structure were developed as novel fluorescence chemosensors with high sensitivity and selectivity toward H+ in solution and acidic atmosphere as well as Al3+ in the presence of other cations. The fluorescence turn-on mechanism was studied and proved to be based on the C=N isomerization. For these fluorescent molecules with donor-acceptor structure, their luminescent wavelength and photophysical properties can be dominated by adjusting the structure of aniline-like groups and the chain length connecting with naphthalimide. All of these fluorescent molecules emitted strong solid-state fluorescence due to their inherent twisted geometries, and exhibited excellent thermal stability, which is beneficial for their application at high temperature.
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