期刊
DESALINATION
卷 515, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.desal.2021.115202
关键词
Brackish water; Desalination; Recovery ratio; Ion exchange; Mg(2+)addition
资金
- BIRD [2029911]
- Israeli Ministry of Energy [21711031]
The study focused on increasing the maximum recovery ratio of brackish water RO desalination plants by using a cationic ion-exchange resin to exchange Ca2+ with Mg2+ and Na+ ions in the raw water, and regenerating it with seawater. Through simulations, the goal of reducing [Ca2+] and enriching the product water with Mg2+ was achieved at no additional cost. The maximal recovery ratio was shown to be raised to 89.2% with a cost reduction of -$0.23 per additional m3 of desalinated water produced.
The maximal recovery ratio of brackish water RO desalination plants located on the coastline can be significantly increased by exchanging Ca2+ with Mg2+ and Na+ ions in the raw water by passing the water through a cationic ion-exchange (CIX) resin which is thereafter regenerated with seawater. The concept allows also enriching the product water with Mg2+, at no additional cost. The Ca2+ fraction (equivalent-based) attached to the CIX resin at equilibrium with seawater was merely -10% of its total capacity, much lower than Na+ (59%) and Mg2+ (28%). The process was simulated on the Sabha-Eilat BWRO plant (Israel) water with the goal of reducing [Ca2+] from -850 to -450 mg/L using a breakthrough/seawater-regeneration sequence. The goal was met by applying a 60 bed-volume (BV) breakthrough-step followed by 20-BV seawater regeneration (HRT = 6 min). -2% of the CIXmended water bypassed the RO step to provide 10 mg Mg/L in the product water. Simulating the maximal recovery ratio showed that it could be raised to 89.2%. A general design and cost-analysis revealed that the cost of each additional m3 of desalinated water produced by the new method was -$0.23, -14% more water is produced and retentate production is -50% lower.
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