期刊
DALTON TRANSACTIONS
卷 51, 期 3, 页码 817-830出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1dt03746c
关键词
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资金
- Spanish Ministerio de Ciencia e Innovacion (MICINN/FEDER) [PID2019-103965GB-I00/AEI/10.13039/501100011033]
- Departamento de Ciencia, Universidad y Sociedad del Conocimiento del Gobierno de Aragon [E42_20R]
This article highlights recent developments on the application of transition metal-based zwitterionic complexes in catalysis, including selected zwitterionic catalysts in polymerization reactions and advances in hydrogenation/dehydrogenation reactions related to energy applications.
This frontiers article highlights recent developments on the application of transition metal-based zwitterionic complexes in catalysis. Recent applications of selected zwitterionic catalysts in polymerization reactions, including the carbonylative polymerization of cyclic ethers, carbon-carbon coupling reactions, the asymmetric hydrogenation of unfunctionalized olefins, and the hydrofunctionalization of alkenes are reviewed. In addition, advances in the field of hydrogenation/dehydrogenation reactions related to energy applications, including the hydrogenation of CO2 and the dehydrogenation of formic acid and N-heterocycles, the functionalization of CO2 with amines and hydrosilanes, and the valorization of polyfunctional bio-based feedstocks, such as the dehygrogenation of glycerol to lactic acid or the reduction of levulinic acid into gamma-valerolactone, are also described.
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