期刊
CRYSTAL GROWTH & DESIGN
卷 21, 期 12, 页码 7098-7103出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.1c00992
关键词
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资金
- National Natural Science Foundation of China [21975255, 51890862, 21921001]
- NSF of Fujian Province [2019J01020758]
- Youth Innovation Promotion Association CAS [2019303]
The first examples of metal trifluoroiodates have been synthesized, featuring windmill-shaped polyfluoroiodate anions. The optical performance measurements show that these compounds exhibit excellent comprehensive performance, making them promising optical crystals in the near-ultraviolet and mid-infrared regions.
The first examples of metal trifluoroiodates, namely, M4O(IO3)(3)(I3O7F3)BF4 (M = Pb, Sr), have been synthesized. Both compounds feature an interesting windmill-shaped [I3O7F3](2-)trimer polyfluoroiodate anion. Optical performance measurements revealed that M4O(IO3)(3)(I3O7F3)BF4 (M = Pb, Sr) exhibits excellent comprehensive performance, which indicates that it is a promising optical crystal in the near-ultraviolet and mid-infrared regions.
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