4.7 Article

Influence of artificial aging on corrosion of abraded Al-Zn-Mg-Cu alloys

期刊

CORROSION SCIENCE
卷 191, 期 -, 页码 -

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2021.109745

关键词

Aluminum alloy; Subsurface; Microstructure; Polarization; Transmission electron microscopy; Atom probe tomography

资金

  1. U.S. Department of Energy [DE-AC05-00OR22725]

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The study demonstrated that surface abrasion creates altered surface layers (ASLs) on various types of aluminum alloys, which have lower corrosion resistance. High temperature treatments can enhance the precipitation of eta phase in the ASL, leading to an increase in ASL breakdown potential by decreasing the zinc content in the ASL solid solution.
Surface abrasion has been shown to create altered surface layers (ASLs) that are hundreds of nm thick on all types of Al alloys. Such ASLs have lower corrosion resistance than the underlying substrate of Al-Zn-Mg-Cu alloys. Here, we demonstrate how heat treatments affect the ASL microstructure on abraded Al-Zn-Mg-Cu alloys using transmission electron microscopy and atom probe tomography, and also how the corrosion properties change using electrochemical polarization. High temperature treatments on the abraded bulk samples enhance eta phase precipitation in the ASL, leading to a decreased Zn content in the ASL solid solution, which ennobles the ASL breakdown potential.

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