期刊
COORDINATION CHEMISTRY REVIEWS
卷 453, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2021.214315
关键词
Alkynyl ligands; Metal clusters; Luminescence; Chirality; Catalysis; Functionalization
资金
- National Natural Science Foundation of China [21825106, 92061201, 21975065]
- Program for Innovative Research Team (in Science and Technology) in Universities of Henan Province [19IRTSTHN022]
- Zhengzhou University
This review summarizes the development and functional properties of alkynyl-protected coinage metal clusters, and discusses the prospects and opportunities for future development.
The selection of surface organic ligands is very important for the preparation of coinage metal clusters with precise structures, which can dictate the related properties of metal clusters. Alkynyl ligands, as a class of protecting ligands in metal cluster systems, have been gaining attentions because of the characteristics of both pi and sigma coordination modes. Specially, alkynyl-protected coinage metal clusters possess rich properties. However, there is no review to systemically summarize the functional properties and structure-functionality correlations of alkynyl-protected coinage metal clusters. In this review, the development of alkynyl ligands for the preparation of coinage metal clusters was reviewed. Additionally, the synthetic approaches of the alkynyl-protected coinage metal clusters were provided. Then, the functional properties of the alkynyl-protected coinage metal clusters were comprehensively summarized. In the end, the prospects and opportunities for the future development were discussed. We believed that the review will motivate the development of functionality-oriented alkynyl-protected coinage metal clusters. (C) 2021 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据