4.8 Review

Oxo/imido heterometathesis: From molecular stoichiometric studies to well-defined heterogeneous catalysts

期刊

COORDINATION CHEMISTRY REVIEWS
卷 448, 期 -, 页码 -

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2021.214112

关键词

Imido; Oxo; Metathesis; Heterometathesis; Cycloaddition; Surface Organometallic Chemistry

资金

  1. Russian Science Foundation [19-73-10163]
  2. Ministry of Science and Higher Education of the Russian Federation

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The review summarizes literature examples of stoichiometric oxo/imido heterometathesis reactions and discusses the current progress in catalytic oxo/imido heterometathesis development, with a focus on preparing highly efficient catalysts based on silica-supported early transition metal oxo and imido complexes using Surface Organometallic Chemistry approach.
Oxo/imido heterometathesis is a class of reactions that interconvert terminal transition metal oxo and imido complexes via [2 + 2] cycloaddition/cycloreversion with heteroolefins and heterocumulenes containing oxo and imino groups. In this review we summarize the literature examples of stoichiometric oxo/imido heterometathesis reactions of imido complexes with different oxo substrates and discuss the current progress in the development of catalytic oxo/imido heterometathesis. In particular, we show how application of Surface Organometallic Chemistry approach allows preparation of highly efficient oxo/imido heterometathesis catalysts based on well-defined silica-supported early transition metal oxo and imido complexes. (C) 2021 Elsevier B.V. All rights reserved.

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