4.7 Article

Kinetics study of ultrasound-assisted chloride release from cementitious materials

期刊

CONSTRUCTION AND BUILDING MATERIALS
卷 317, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.conbuildmat.2021.125968

关键词

Ultrasound; Chloride release; Chloride binding; Cementitious materials

资金

  1. National Natural Science Foundation of China [52071130]
  2. Natural Science Foundation of Jiangsu Province [BK20211204]
  3. Open Research Fund of Key Laboratory of Construction and Safety of Water Engineering of the Ministry of Water Resources, China Institute of Water Resources and Hydropower Research [202008]
  4. Nantong Science and Technology Project [JC2020093]

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This study investigated the influence of ultrasound on chloride release from cementitious materials. The results showed that ultrasound power enhanced both the equilibrium point and release rate of chloride, while ultrasound frequency mainly promoted the release rate. Kinetics analysis demonstrated that the chemical reaction step controlled chloride release, and its dominance was not weakened by ultrasound. Interestingly, physically bound chlorides decomposed faster than chemically bound ones after ultrasound irradiation. Overall, the findings clearly demonstrated the beneficial effect of ultrasonic waves on improving chloride release from cementitious materials.
This paper studied the influence of ultrasound on chloride release from cementitious materials. Results showed that ultrasound power enhanced both equilibrium point and chloride release rate, while ultrasound frequency mainly promoted the release rate. Kinetics analysis demonstrated that chloride release was controlled by the chemical reaction step. Its dominant role was not weakened by ultrasound. A decrease of physically and chemically bound chlorides was found after ultrasound irradiation. Interestingly, the physically bound chlorides decomposed faster than the chemically bound ones. Overall findings clearly demonstrated that ultrasonic waves had a beneficial effect on improving the chloride release from cementitious materials.

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