Influence of dipotassium hydrogen phosphate on properties of magnesium potassium phosphate cement

Magnesium potassium phosphate cement (MKPC) is usually prepared from dead burned magnesia (MgO) and potassium dihydrogen phosphate (KH2PO4, KDP). Here, MKPC was produced by mixing KDP and dipotassium hydrogen phosphate trihydrate (K2HPO4 center dot 3H(2)O, DKP) as phosphates. To study the influence of DKP on the hydration process and hardening, pH values, wettability between magnesia and initial solutions, hydration temperature development, initial setting time, fluidity, hydration products, and mechanical properties were measured. The results show that the decrease in the ratio of KDP to DKP leads to an increase in pH and a decrease in wettability, resulting in changes in the hydration process. In addition, setting behavior is also influenced by the ratio of KDP to DKP. When KDP/DKP>2:1, as the ratio becomes smaller, the initial setting time gets shorter; otherwise, the opposite is true. These differences are attributable to the temperature change during the reaction, the distinction in wettability, and the different pH caused by the various ratios of KDP to DKP. Moreover, XRD analysis shows that the hydrated products are still MgKPO4 center dot xH(2)O (x =1 or 6), indicating that hydration products are basically unaffected. TGA analysis signifies that the amount of hydrated products in MKPC is responsible for the changes in the mechanical properties.

Automated summary

This study investigated the influence of dipotassium hydrogen phosphate trihydrate (DKP) on the hydration process and hardening of magnesium potassium phosphate cement (MKPC). It was found that the ratio of DKP to potassium dihydrogen phosphate (KDP) affects the pH and wettability of the solutions, leading to changes in the hydration process. The setting behavior is also influenced by the ratio. Moreover, the hydrated products are basically unaffected, but the amount of hydrated products in MKPC is responsible for the changes in the mechanical properties.