期刊
CONSTRUCTION AND BUILDING MATERIALS
卷 303, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.conbuildmat.2021.124523
关键词
Geopolymer; Sulfuric acid attack; Electrochemical impedance spectroscopy; Mechanical properties; Phase composition; Microstructure
资金
- National Natural Science Foundation of China [51879180,41807256]
The performance and degradation mechanism of geopolymer in sulfuric acid solution were studied. With prolonged immersion time, the impedance arc diameter of the geopolymer decreased, and there was a significant correlation between compressive strength and impedance parameters. Microstructural examination indicated that the deterioration of geopolymer was associated with depolymerization of aluminosilicate polymers and destruction of microstructure in acidic media, leading to strength loss.
The performance of the geopolymer synthesized using red mud and coal metakaolin when exposed to sulfuric acid solutions was evaluated. The effects of different soaking times on mechanical properties, electrochemical properties, and microstructural changes to the materials were investigated. The degradation of the geopolymer was studied using corrosion depth and weight testing, uniaxial compression test, electrochemical impedance spectroscopy (EIS), nuclear magnetic resonance (NMR), X-ray diffractometry (XRD), and scanning electron microscope-energy dispersive spectrometry (SEM-EDS). The EIS results indicate that the diameter of the impedance arc in the intermediate frequency region decreases with prolonged immersion. In addition, there was a significant correlation between the compressive strength and the impedance parameters (Rs and R1). Microstructural examination showed that the deterioration of the geopolymer observed was connected to depolymerization of the aluminosilicate polymers and destruction of microstructure in acidic media, which lead to loss of strength.
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