期刊
COMPOSITES PART B-ENGINEERING
卷 224, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.compositesb.2021.109230
关键词
A; Acetic acid; E; Carbon fiber reinforced polymer; E; Swelling; E; Recycle
资金
- National Natural Science Founds of China [51508165]
- Science and Technology Research Key Project for development and promotion [212102310061]
- Henan polytechnic university [B2014-073, B2015-22]
- Young key teachers fund project of Henan polytechnic university [2016XQG-04]
Compared to thermal or chemical recycling, mechanical recycling of CFRP is simpler and more cost-effective, with reduced environmental pollution. By using acetic acid, this study successfully achieved full swelling and slight degradation of cured epoxy resin in CFRP, preserving the length and strength of carbon fibers. The recycled products showed excellent reinforcing properties and can be used to prepare new CFRP products through hot pressing, with flexural strength reaching up to 47%-89% of the original CFRP board.
Compared with thermal or chemical recycling, the mechanical recycling of the carbon fiber-reinforced polymer (CFRP) is simpler, more economical, and produces less environmental pollution. However, the recycled products of mechanical recycling are only fillers or short fibers with poor reinforcing properties. In this study, acetic acid was used to achieve the full swelling and slight degradation of cured epoxy resin (CEP) in CFRP. The stiff CFRP became soft in the acetic acid medium at 140 degrees C, and it delaminated into soft single CFRP layers at 160 degrees C-220 degrees C within 1 h. Thus, the swollen CFRP can be easily cut into long strips, large thin slices, or other customized shapes. The length and strength of the carbon fibers were preserved well during the reusing process. The shear and delamination products exhibited excellent reinforcing properties, and they can be prepared into new CFRP products through hot pressing. The flexural strength of a newly prepared CFRP board can reach 47%-89% that of the original CFRP board. The swelling and degradation characteristics and mechanism of CEP in acetic acid were also investigated in this study. Thus, this work provides a novel method for recycling thermosetting composites.
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