Flexible multilayered aramid nanofiber/silver nanowire films with outstanding thermal durability for electromagnetic interference shielding

Multilayered aramid nanofiber/silver nanowire (ANF/AgNW) films using AgNW as internal conductive layers and ANF as outer protective layers were fabricated via a multiple filtration layer-by-layer process and subsequent hot-pressing. The electromagnetic interference (EMI) shielding and mechanical properties of the multilayered ANF/AgNW films were significantly improved through hydrogen bonding between adjacent layers, and EMI shielding properties were accordingly enhanced owing to the internal multiple reflection of electromagnetic waves between AgNW layers. The 7layer structure ANF/AgNW films exhibited excellent mechanical properties with a tensile strength of 79 MPa and fracture strain of 4.6%, high EMI shielding effectiveness of 63.3 dB, attributing mainly to the synergetic effect of intrinsic mechanical strength of ANF and excellent electrical conductivity of the tightly interconnected AgNW network. In addition, the multilayered films which have excellent stability for EMI shielding properties at high temperature (similar to 400 degrees C) are better than traditional polymer-based EMI shielding materials.

Automated summary

The multilayered aramid nanofiber/silver nanowire films prepared by combining silver nanowires with aramid nanofibers exhibit excellent EMI shielding and mechanical properties, attributed to hydrogen bonding between layers and internal reflection of electromagnetic waves within the silver nanowire layers. These multilayered films demonstrate outstanding stability and performance advantages at high temperatures.