Heterogeneous activation of peroxymonosulfate by Co3O4 loaded biochar for efficient degradation of 2,4-dichlorophenoxyacetic acid

Review Engineering, Environmental

A review of the innovations in metal- and carbon-based catalysts explored for heterogeneous peroxymonosulfate (PMS) activation, with focus on radical vs . non-radical degradation pathways of organic contaminants

Mona Kohantorabi et al.

Summary: This review summarizes the rapid development of heterogeneous catalysts for peroxymonosulfate (PMS) activation in sulfate radical-based AOPs, covering various catalysts and discussing their roles in the activation mechanism.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Environmental Sciences

Manganese release from corrosion products of cast iron pipes in drinking water distribution systems: Effect of water temperature, pH, alkalinity, SO42- concentration and disinfectants

Shengnan Zhang et al.

Summary: The release of manganese from corrosion scales in drinking water distribution systems is influenced by factors such as pH, alkalinity, temperature, and sulfate concentration, with disinfectants found to inhibit manganese release. Sulfate concentration and alkalinity are significantly important in controlling manganese release, while pH and disinfectant type also play a significant role. Further investigation of the impact of disinfectants on manganese release in DWDSs is necessary for better understanding and management of water quality.

CHEMOSPHERE (2021)

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Article Environmental Sciences

Highly specific nanobody against herbicide 2,4-dichlorophenoxyacetic acid for monitoring of its contamination in environmental water

Zhen-Feng Li et al.

Summary: The study successfully developed a nanobody-based immunoassay for monitoring trace levels of 2,4-D in the environment. Utilizing a step-wise strategy from hapten design to nanobody-AP fusion production, the research achieved successful results, demonstrating the method as a convenient and practical tool for monitoring 2,4-D residuals.

SCIENCE OF THE TOTAL ENVIRONMENT (2021)

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Review Engineering, Environmental

A review of the recent advances on the treatment of industrial wastewaters by Sulfate Radical-based Advanced Oxidation Processes (SR-AOPs)

Stefanos Giannakis et al.

Summary: SR-AOPs have gained significant attention in recent years for their versatility and efficacy in disinfection and decontamination. These processes, which generate sulfate radicals or sulfate and hydroxyl radicals, have been successfully applied in the treatment of various industrial wastewater, providing a potential solution for better wastewater treatment practices.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Engineering, Environmental

The mechanism changes during bisphenol A degradation in three iron functionalized biochar/peroxymonosulfate systems: The crucial roles of iron contents and graphitized carbon layers

Kai Li et al.

Summary: Three magnetic biochar nanocomposites were prepared with different catalytic performances for bisphenol A degradation, where C800-3 showed the best performance. The dominant role of electron transfer pathway was gradually replaced by the SO4 center dot- pathway with the increase of iron amount and the destruction of graphitized carbon layers.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Engineering, Environmental

Effect of inorganic anions on the performance of advanced oxidation processes for degradation of organic contaminants

Jianlong Wang et al.

Summary: Inorganic anions such as chloride, carbonate, phosphate, sulfate, and nitrate have a significant impact on the performance of Advanced Oxidation Processes (AOPs). This influence is not solely attributed to their quenching effect, but also affects reactive species, oxidant stability, catalyst activity, and degradation products. Understanding the comprehensive evaluation of the effect of inorganic anions on AOPs is crucial for optimizing the treatment of organic pollutants.

CHEMICAL ENGINEERING JOURNAL (2021)

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Review Engineering, Environmental

Burgeoning prospects of biochar and its composite in persulfate-advanced oxidation process

Yanlan Zhao et al.

Summary: Biochar and its composites play a crucial role as catalysts in persulfate-advanced oxidation process, effectively removing organic pollutants through adsorption and catalysis. The study focused on the influence of the physicochemical properties of biochar on persulfate activation, and emphasized the key role of biochar in affecting the catalytic properties of BCs, including stabilizing nanoparticles, expanding surface area, increasing active sites, and regulating electron transfer reactions.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Engineering, Environmental

Electron transfer enhancing Fe(II)/Fe(III) cycle by sulfur and biochar in magnetic FeS@biochar to active peroxymonosulfate for 2,4-dichlorophenoxyacetic acid degradation

Qiaofeng Hong et al.

Summary: A highly active mediator (MFB) based on FeS@biochar was prepared for peroxymonosulfate (PMS) activation, showing excellent performance in degrading 2,4-D pesticides with enhanced lifetime. The optimized reaction parameters were determined, and a novel kinetics model was proposed for describing the interfacial adsorption and catalytic reaction process accurately. The study also highlighted the inhibitory effects of pH and coexisting anions on 2,4-D degradation, providing a promising approach for designing high-performance mediators in environmental remediation.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Evaluation of peroxymonosulfate/O3/UV process on a real polluted water with landfill leachate: Feasibility and comparative study

Farshid Ghanbari et al.

Summary: The study found that the PMS/O-3/UV process showed high efficiency in removing hazardous materials such as TOC, COD, color, and ammonia from polluted landfill leachate. The addition of ferrous ions increased TOC removal efficiency, while cobalt ions had no significant effect. The process followed a pseudo-first-order kinetic model with a reaction rate constant of 0.0203 min(-1). Compared to peroxone/UV, PMS/O-3/UV demonstrated superior performance in removing pollutants from low volume polluted water.

KOREAN JOURNAL OF CHEMICAL ENGINEERING (2021)

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Article Engineering, Environmental

Large-Scale Synthesis of Biomass@MOF-Derived Porous Carbon/Cobalt Nanofiber for Environmental Remediation by Advanced Oxidation Processes

Ming Zhang et al.

Summary: In this study, a highly efficient carbon-based nanocatalyst CC@CNCo was successfully prepared using cotton as an ideal support for MOFs, and used for the removal of pollutants such as bisphenol A. The results showed that the catalyst could remove nearly 100% of BPA within 5 minutes, indicating great potential for environmental remediation.

ACS ES&T ENGINEERING (2021)

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Review Chemistry, Multidisciplinary

Single-atom catalysis in advanced oxidation processes for environmental remediation

Yanan Shang et al.

Summary: Carbon-based single atom catalysts show high performances and efficiency in environmental catalysis, but there is a lack of comprehensive research on their catalytic sites and mechanisms in advanced oxidation processes, which is necessary for further exploration.

CHEMICAL SOCIETY REVIEWS (2021)

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Review Environmental Sciences

Analysis of global trends and gaps for studies about 2,4-D herbicide toxicity: A scientometric review

Natana Raquel Zuanazzi et al.

CHEMOSPHERE (2020)

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Review Engineering, Environmental

Persulfate-Based Advanced Oxidation: Critical Assessment of Opportunities and Roadblocks

Jaesang Lee et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2020)

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Article Engineering, Environmental

Facile synthesis of pure g-C3N4 materials for peroxymonosulfate activation to degrade bisphenol A: Effects of precursors and annealing ambience on catalytic oxidation

Chaoting Guan et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Environmental

Enhanced photocatalytic degradation of acephate pesticide over MCM-41/Co3O4 nanocomposite synthesized from rice husk silica gel and Peach leaves

Mostafa R. AbuKhadra et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

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Article Engineering, Environmental

Degradation mechanism of norfloxacin in water using persulfate activated by BC@nZVI/Ni

Fang Zhu et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Environmental

Transforming goat manure into surface-loaded cobalt/biochar as PMS activator for highly efficient ciprofloxacin degradation

Junmei Luo et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Environmental

Efficient activation of peroxydisulfate (PDS) by rice straw biochar modified by copper oxide (RSBC-CuO) for the degradation of phenacetin (PNT)

Wei Li et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Environmental Sciences

Enhanced electrochemical degradation of 2,4-dichlorophenol with the assist of hydrochar

Weiming Cao et al.

CHEMOSPHERE (2020)

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Article Engineering, Environmental

Unraveling the Overlooked Involvement of High-Valent Cobalt-Oxo Species Generated from the Cobalt(II)-Activated Peroxymonosulfate Process

Yang Zong et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2020)

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Article Biotechnology & Applied Microbiology

Acetaminophen removal from aqueous solutions through peroxymonosulfate activation by CoFe2O4/mpg-C3N4 nanocomposite: Insight into the performance and degradation kinetics

Aydin Hassani et al.

ENVIRONMENTAL TECHNOLOGY & INNOVATION (2020)

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Article Engineering, Environmental

New insights into the formation and transformation of active species in nZVI/BC activated persulfate in alkaline solutions

Haoyu Luo et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Review Chemistry, Physical

Advanced Design and Synthesis of Composite Photocatalysts for the Remediation of Wastewater: A Review

Jianlong Ge et al.

CATALYSTS (2019)

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Article Environmental Sciences

Fabrication of novel magnetic MnFe2O4/bio-char composite and heterogeneous photo-Fenton degradation of tetracycline in near neutral pH

Cui Lai et al.

CHEMOSPHERE (2019)

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Article Engineering, Environmental

Activation mechanism of peroxymonosulfate by biochar for catalytic degradation of 1,4-dioxane: Important role of biochar defect structures

Da Ouyang et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Review Engineering, Environmental

Recent advances in biochar-based catalysts: Properties, applications and mechanisms for pollution remediation

Rong-Zhong Wang et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Engineering, Environmental

Fabrication of Fe3O4 and graphitized porous biochar composites for activating peroxymonosulfate to degrade p-hydroxybenzoic acid: Insights on the mechanism

Haichao Fu et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Toxicology

Kinetics of the metabolic effects, distribution spaces and lipid-bilayer affinities of the organo-chlorinated herbicides 2,4-D and picloram in the liver

Gabriela Bueno Franco Salla et al.

TOXICOLOGY LETTERS (2019)

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Article Chemistry, Physical

Effect of Residual Chlorine on the Catalytic Performance of Co3O4 for CO Oxidation

Muhong Li et al.

ACS CATALYSIS (2019)

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Article Engineering, Environmental

Heterogeneous Fe2CoTi3O10-MXene composite catalysts: Synergistic effect of the ternary transition metals in the degradation of 2,4-dichlorophenoxyacetic acid based on peroxymonosulfate activation

Mingmei Ding et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Chemistry, Physical

Characterization of biochar derived from rice husks and its potential in chlorobenzene degradation

Kaikai Zhang et al.

CARBON (2018)

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Article Chemistry, Physical

Biomass carbon modified Z-scheme g-C3N4/Co3O4 heterojunction with enhanced visible-light photocatalytic activity

Xiaoxu Zhao et al.

CATALYSIS COMMUNICATIONS (2018)

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Review Engineering, Environmental

Activation of persulfate (PS) and peroxymonosulfate (PMS) and application for the degradation of emerging contaminants

Jianlong Wang et al.

CHEMICAL ENGINEERING JOURNAL (2018)

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Article Environmental Sciences

Insights into the mechanism of persulfate activated by rice straw biochar for the degradation of aniline

Yao Wu et al.

CHEMOSPHERE (2018)

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Article Engineering, Environmental

Biochar modification significantly promotes the activity of Co3O4 towards heterogeneous activation of peroxymonosulfate

Liwei Chen et al.

CHEMICAL ENGINEERING JOURNAL (2018)

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Article Engineering, Environmental

Coupling electrooxidation and Oxone for degradation of 2,4-Dichlorophenoxyacetic acid (2,4-D) from aqueous solutions

Nematollah Jaafarzadeh et al.

JOURNAL OF WATER PROCESS ENGINEERING (2018)

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Article Engineering, Environmental

Rice husks as a sustainable silica source for hierarchical flower-like metal silicate architectures assembled into ultrathin nanosheets for adsorption and catalysis

Shouwei Zhang et al.

JOURNAL OF HAZARDOUS MATERIALS (2017)

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Article Engineering, Environmental

Synergistic degradation of phenols using peroxymonosulfate activated by CuO-Co3O4@MnO2 nanocatalyst

Aimal Khan et al.

JOURNAL OF HAZARDOUS MATERIALS (2017)

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Article Engineering, Environmental

Efficient degradation of 2,4-dichlorophenoxyacetic acid by peroxymonosulfate/magnetic copper ferrite nanoparticles/ozone: A novel combination of advanced oxidation processes

Nematollah Jaafarzadeh et al.

CHEMICAL ENGINEERING JOURNAL (2017)

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Article Engineering, Environmental

Degradation of 2,4-dichlorophenoxyacetic acid in water by persulfate activated with FeS (mackinawite)

Hai Chen et al.

CHEMICAL ENGINEERING JOURNAL (2017)

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Article Engineering, Environmental

Heterogeneous activation of peroxymonosulfate using ordered mesoporous Co3O4 for the degradation of chloramphenicol at neutral pH

Jing Deng et al.

CHEMICAL ENGINEERING JOURNAL (2017)

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Article Chemistry, Physical

Activation of peroxymonosulfate by carbonaceous oxygen groups: experimental and density functional theory calculations

Yuxian Wang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2016)

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Review Environmental Sciences

Engineered/designer biochar for contaminant removal/immobilization from soil and water: Potential and implication of biochar modification

Anushka Upamali Rajapaksha et al.

CHEMOSPHERE (2016)

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Article Ecology

Rice husk as a low cost nanosorbent for 2,4-dichlorophenoxyacetic acid removal from aqueous solutions

Evy Alice M. Abigail et al.

ECOLOGICAL ENGINEERING (2016)

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Article Environmental Sciences

Toxic and genotoxic effects of the 2,4-dichlorophenoxyacetic acid (2,4-D)-based herbicide on the Neotropical fish Cnesterodon decemmaculatus

C. Ruiz de Arcaute et al.

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY (2016)

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Article Engineering, Environmental

Sulfate Radical-Mediated Degradation of Sulfadiazine by CuFeO2 Rhombohedral Crystal-Catalyzed Peroxymonosulfate: Synergistic Effects and Mechanisms

Yong Feng et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2016)

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Article Engineering, Environmental

Magnetic CoFe2O4 nanoparticles supported on titanate nanotubes (CoFe2O4/TNTs) as a novel heterogeneous catalyst for peroxymonosulfate activation and degradation of organic pollutants

Yunchen Du et al.

JOURNAL OF HAZARDOUS MATERIALS (2016)

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Article Chemistry, Applied

Diffusion mediated selective adsorption of Zn2+ from artificial seawater by MCM-41

Aneesh Mathew et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2016)

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Article Engineering, Environmental

Heterogeneous fenton-like catalytic degradation of 2,4-dichlorophenoxyacetic acid in water with FeS

Hai Chen et al.

CHEMICAL ENGINEERING JOURNAL (2015)

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Article Multidisciplinary Sciences

Reversible adapting layer produces robust single-crystal electrocatalyst for oxygen evolution

Ching-Wei Tung et al.

NATURE COMMUNICATIONS (2015)

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Article Nanoscience & Nanotechnology

MOF-Templated Synthesis of Porous Co3O4 Concave Nanocubes with High Specific Surface Area and Their Gas Sensing Properties

Yinyun Lu et al.

ACS APPLIED MATERIALS & INTERFACES (2014)

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Article Engineering, Environmental

Degradation of chloramphenicol by thermally activated persulfate in aqueous solution

Minghua Nie et al.

CHEMICAL ENGINEERING JOURNAL (2014)

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Article Engineering, Environmental

Impact of activation methods on persulfate oxidation of methyl tert-butyl ether

Dayi Deng et al.

JOURNAL OF HAZARDOUS MATERIALS (2014)

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Article Engineering, Environmental

2,4-D adsorption to biochars: Effect of preparation conditions on equilibrium adsorption capacity and comparison with commercial activated carbon literature data

J. P. Kearns et al.

WATER RESEARCH (2014)

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Article Chemistry, Physical

A sandwich N-doped graphene/Co3O4 hybrid: an efficient catalyst for selective oxidation of olefins and alcohols

Renfeng Nie et al.

JOURNAL OF MATERIALS CHEMISTRY A (2013)

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Article Nanoscience & Nanotechnology

Nanocrystal-Constructed Mesoporous Single-Crystalline Co3O4 Nanobelts with Superior Rate Capability for Advanced Lithium-Ion Batteries

Hui Huang et al.

ACS APPLIED MATERIALS & INTERFACES (2012)

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Article Agricultural Engineering

Biotransformation of p-coumaric acid and 2,4-dichlorophenoxy acetic acid by Azotobacter sp strain SSB81

Samiran S. Gauri et al.

BIORESOURCE TECHNOLOGY (2012)

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Article Chemistry, Physical

An easily recyclable Co/SBA-15 catalyst: Heterogeneous activation of peroxymonosulfate for the degradation of phenol in water

Longxing Hu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2011)

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Article Chemistry, Physical

Activated carbon supported cobalt catalysts for advanced oxidation of organic contaminants in aqueous solution

Pradeep R. Shukla et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2010)

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Article Engineering, Environmental

Transitional adsorption and partition of nonpolar and polar aromatic contaminants by biochars of pine needles with different pyrolytic temperatures

Baoliang Chen et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2008)

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Article Chemistry, Physical

Highly dispersed PTFE/Co3O4 flexible films as photocatalyst showing fast kinetic performance for the discoloration of azo-dyes under solar irradiation

P. Raja et al.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2007)

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Heterogeneous activation of peroxymonosulfate by Co3O4 loaded biochar for efficient degradation of 2,4-dichlorophenoxyacetic acid

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