Distinct liquid crystal self-assembly behavior of cellulose nanocrystals functionalized with ionic liquids

Rod-like cellulose nanocrystals (CNCs) show the intriguing liquid crystal self-assembly ability. The understanding of the self-assembly behavior of CNCs is of fundamental importance for constructing cellulose-based functional materials. The presented work explores how the liquid crystal self-assembly behavior of CNCs is affected by the grafted ionic liquids (IL) [VBIm] [BF4]. The results demonstrate that the IL modified CNC (CNC-IL) with positive charged form chiral nematic structure in suspensions, which was normally observed in negative charged ones. Significantly, such liquid-crystalline organization can be obtained under much lower concentration (as low as 1.0 wt%) than that of the non-functionalized CNCs prepared from paper pulp (similar to 3.0 wt%). Moreover, for CNC-IL concentrations varying from 1.0 to 4.0 wt%, the tactoids (showing obvious fingerprint texture) coexist with the disordered CNC phase, rather than separating into two phases. Unlike original CNCs, the pitch of chiral nematic tactoids increases with increasing concentration of CNC-IL. Our study suggests that the distinct liquid crystal self-assembly behavior of CNC-IL is related to the restricted mobility of CNCs rods due to the increase in CNCs particle size and the high viscosity of CNC-IL suspension as the result of IL surface modification. The study of the liquid crystal assembly behavior of IL modified CNCs provides some new insight to understand the intriguing chiral nematic self-assembly of CNCs and for construction of CNC-IL reinforced nanocomposites.

Automated summary

The study investigates the impact of ionic liquids (IL) on the liquid crystal self-assembly behavior of cellulose nanocrystals (CNCs). Results demonstrate that CNCs modified with positively charged IL (CNC-IL) can form chiral nematic structures at lower concentrations, showing distinct assembly behavior compared to original CNCs.