期刊
CHINESE CHEMICAL LETTERS
卷 33, 期 8, 页码 4033-4036出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2021.12.051
关键词
Reversible photodimerization; Superstructures; Coumarin; Supramolecular self-assembly; Molecular stacking
资金
- National Natural Science Foundation of China [21861132001, 21772099, 21772100]
This study presents a rational construction of fine-tuning and precisely controllable topological nanostructures based on a supramolecular self-assembly system. The use of coumarin-12-crown-4 as a building block allows for reversible high stereo-selective photodimerization and photocleavage, leading to the formation of helical nanobelts and nanoballs. The transformation of superstructures based on photo-controlled multiple blocks provides insights into the relationship between molecules and superstructures.
Rational construction of fine-tuning and precisely controllable topological nanostructures based on supramolecular self-assembly system remains a challenge. Herein, coumarin-12-crown-4 (1) as a building block was synthesized by one-pot method and showed reversible high stereo-selective photodimerization (anti-head-to-head dimer (anti-HH-1): syn-head-to-head dimer (syn-HH-1)= 10.8:1) and photocleavage. Helical nanobelts were formed by the self-assembly of 1 through asymmetrical H-bonds, which were in concordance with the crystal state superstructure. Upon irradiation with 365 nm light, these nanobelts transformed into nanoballs which were constructed by three building blocks. Further, we investigated the photoreaction of 1 and got two pure covalent dimers (anti-HH-1 and syn-HH-1). The anti-HH-1 selfassembled into hollow micro-vesicles. The transformation of superstructures based on photo-controlled multiple blocks shines a light to the research on the relationship between molecules and superstructures. (C) 2022 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
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