Recent Advances in Reductive Upgrading of 5-Hydroxymethylfurfural via Heterogeneous Thermocatalysis

The catalytic conversion of 5-hydroxymethylfufural (HMF), one of the vital platform chemicals in biomass upgrading, holds great promise for producing highly valuable chemicals through sustainable routes, thereby alleviating the dependence on fossil feedstocks and reducing CO2 emissions. The reductive upgrading (hydrogenation, hydrogenolysis, ring-opening, ring-rearrangement, amination, etc.) of HMF has exhibited great potential to produce monomers, liquid fuel additives, and other valuable chemicals. Thermocatalytic conversion has a significant advantage over photocatalysis and electrocatalysis in productivity. In this Review, the recent achievements of thermo-reductive transformation of HMF to various chemicals using heterogeneous catalytic systems are presented, including the catalytic systems (catalyst and solvent), reaction conditions, (reaction temperature, pressure, etc.), and reaction mechanisms. The current challenges and future opportunities are discussed as well, aiming at guiding the catalyst design and practical scalable productions.

Automated summary

The catalytic conversion of 5-hydroxymethylfufural (HMF) holds great promise for producing valuable chemicals and reducing dependence on fossil feedstocks. The reductive upgrading of HMF has shown potential to produce monomers and liquid fuel additives. Thermocatalytic conversion has advantages over photocatalysis and electrocatalysis in productivity. Research focuses on catalyst design, reaction conditions, and mechanisms.