Investigation of mechanism of heavy metals (Cr6+, Pb2+ & Zn2+) adsorption from aqueous medium using rice husk ash: Kinetic and thermodynamic approach

In this work, we examined the possibility on the application of rice husk as biosorbent for the elimination of heavy metal ions (chromium, lead, and zinc) existing in the aqueous solutions. The biosorbent was prepared from rice husk powder and modified with 0.1 N of HCl for creating the functional groups and increase specific surface area. The FT-IR spectra, SEM& EDX studies of rice hulls powder were examined for the pristine adsorbent and after the adsorption of heavy metal ions. The batch adsorption technique was adopted for this work and adsorption parameters were optimized. The maximum efficiency of adsorption is obtained at 6.0 pH, 1 h of contact duration, the rice husk dosage is 2.5 g/L, and temperature of 30 degrees C for 25 mg/L of Cr, Pb & Zn metal ion solutions. The Cr, Pb & Zn metal ions are removed up to 87.12 %, 88.63 % & 99.28 %, respectively, using the rice husk powder. The adsorption process follows the Temkin & D-R isotherm model. Elovich model was fitted against the kinetic data of metal ion adsorption. Based on the experimental observations, the rice husk powder can be considered as a low cost adsorbent for heavy metal ion removal from the industrial effluent.

Automated summary

This study investigated the potential use of rice husk powder as a biosorbent for the removal of heavy metal ions from aqueous solutions. The experimental results showed that under optimized conditions, rice husk powder could effectively remove Cr, Pb, and Zn metal ions with high efficiency. The adsorption process followed the Temkin and D-R isotherm model and Elovich model for kinetic data. Based on the findings, rice husk powder could be considered as a low-cost and efficient adsorbent for heavy metal ion removal from industrial effluent.