Photoelectrocatalytic treatment of levofloxacin using Ti/MMO/ZnO electrode

Here, the antibiotic levofloxacin (LFX) widely used and detected in the environment was degraded by photoelectrolysis using a new electrode based on zinc oxide (ZnO) and a mixture of mixed oxides of ruthenium and titanium (MMO). The influence of the potential and irradiation of UV light was investigated in the photostability of the Ti/MMO/ZnO electrode and in the degradation of the antibiotic. The experiments were conducted at different pH values (5.0, 7.0 and 9.0) in sodium sulfate solution in a glass reactor with central lighting. It was observed that the new Ti/MMO/ZnO electrode has good stability under light irradiation and potential, presenting excellent photocurrent and high photoactivity in LFX photoelectrolysis. The removal efficiency of the compound was directly related to the formation of oxidizing species in solution, the photo-generated charges on the electrode and the electrostatic characteristics of the molecule. The mineralization rate, the formation of reaction intermediates and short chain carboxylic acids (acetic, maleic, oxalic and oxamic acid), in addition to the formation of N-mineral species (NO3- and NH4+) was dependent on the pH of the solution and the investigated processes: photoelectrolysis was more efficient than photolysis, which, in turn, was more efficient than electrolysis. The synergistic effect and the high rate of degradation of LFX after 4.0 h of treatment (100%) observed in photoelectrolysis at alkaline pH, was associated with the high stability of the Ti/MMO/ZnO electrode at this pH, the photoactivation of sulfate ions and the ease generation of oxidizing radicals, such as center dot OH.

Automated summary

The new Ti/MMO/ZnO electrode demonstrated good stability under light irradiation and potential, showing excellent photocurrent and high photoactivity in the photoelectrolysis of LFX. The removal efficiency of the compound was influenced by the formation of oxidizing species, photo-generated charges, and electrostatic characteristics of the molecule. Photoelectrolysis was found to be more efficient than photolysis and electrolysis, with alkaline pH enhancing the degradation of LFX due to the high stability of the Ti/MMO/ZnO electrode, photoactivation of sulfate ions, and generation of oxidizing radicals.