期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 28, 期 19, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202200023
关键词
Hydrogen Atom Transfer; Metal-free processes; Photochemistry; Photoinitiation; PhCOCOOH
资金
- Hellenic Foundation for Research and Innovation (HFRI) [721]
- State Scholarships Foundation (IKY)
- action of the Operational Programme Human Resources Development, Education and Lifelong Learning - European Social Fund (ESF)
- Greek National Resources
- H.F.R.I. [655]
- Supporting Post-Doctoral Researchers-Call B, action of the Operational Programme Human Resources Development, Education and Lifelong Learning [MIS 5033021]
- European Social Fund (ESF)
In this paper, we restudied the mechanism of action of phenylglyoxylic acid (PhCOCOOH) in photochemical reactions and proposed a unified mechanism. Additionally, we compared its action as a photoinitiator with known and commercially available photoinitiators.
Since 2014, we have introduced in literature the use of phenylglyoxylic acid (PhCOCOOH), a small and commercially available organic molecule, as a potent promoter in a variety of photochemical processes. Although PhCOCOOH has a broad scope of photochemical reactions that can promote, the understanding of its mode of action in our early contributions was moderate. Herein, we are restudying and revisiting the mechanism of action of PhCOCOOH in most of these early contributions, providing a unified mechanism of action. Furthermore, the understanding of its action as a photoinitiator opened a new comparison study with known and commercially available photoinitiators.
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