期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 27, 期 72, 页码 18047-18053出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202103371
关键词
density functional calculations; organosilanes; reaction mechanisms; SO2; sulfones
资金
- CEA
- CNRS
- ERC [818260]
- European Research Council (ERC) [818260] Funding Source: European Research Council (ERC)
A new air-tolerant Cu-catalyzed sulfonylative Hiyama cross-coupling reaction for the synthesis of diaryl sulfones has been developed, tolerating a wide range of polar functional groups. Control experiments and DFT calculations elucidated the mechanism involving the formation of a Cu(I)-sulfinate intermediate through fast insertion of a SO2 molecule.
An air-tolerant Cu-catalyzed sulfonylative Hiyama cross-coupling reaction enabling the formation of diaryl sulfones is described. Starting from aryl silanes, DABSO and aryliodides, the reaction tolerates a large variety of polar functional groups (amines, ketones, esters, aldehydes). Control experiments coupled with DFT calculations shed light on the mechanism, characterized by the formation of a Cu(I)-sulfinate intermediate via fast insertion of a SO2 molecule.
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