4.3 Article

Design of Dimeric Dinuclear Boron Complexes with Flexible Linkers: Aggregation-induced White-light Emission via Molecular Engineering

期刊

CHEMISTRY LETTERS
卷 51, 期 3, 页码 300-302

出版社

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.210794

关键词

Boron complexes; White-light emission; Aggregation

资金

  1. JSPS KAKENHI [JP20H04675, JP20K21212, JP21H05400]
  2. Toyota Riken Scholar Program
  3. Samco Foundation
  4. TOBE MAKI Scholarship Foundation

向作者/读者索取更多资源

The study successfully controlled the aggregation state of two new covalently bonded dinuclear boron-based dye complexes to fabricate white-light-emitting materials that exhibit blue and orange emission. One of the complexes has a photoluminescence quantum yield of 16% in the solid state, highlighting the importance of molecular engineering through the control of dye aggregation for creating novel functional materials with interesting optical properties.
The aggregation state of two new covalently bonded dinuclear boron-based dye complexes was controlled to fabricate white-light-emitting materials. The materials exhibit blue and orange emission, with a photoluminescence quantum yield of 16% for one of the complexes in the solid state. This study highlights the importance of molecular engineering through the control of dye aggregation as a fundamental technology for creating novel functional materials with interesting optical properties.

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