期刊
CHEMISTRY LETTERS
卷 50, 期 12, 页码 1993-1996出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.210502
关键词
Borate ester; Dative bond; Polymer
资金
- KAKENHI from the Japan Society for the Promotion of Science (JSPS) [19K15639]
- Grants-in-Aid for Scientific Research [19K15639] Funding Source: KAKEN
Random copolymers with triethanolamine borate (TEAB) groups in the side chains were synthesized and showed superior thermal properties due to the rigid cage structures of TEAB. The pendant TEAB groups were relatively stable to hydrolysis, but quantitatively hydrolyzed in the presence of fluoride anions.
Random copolymers bearing triethanolamine borate (TEAB) groups in the side chains were investigated as the first example of boratrane-containing polymers. The title polymers were synthesized via two steps of polymer reactions from random copolymers of styrene and glycidyl methacrylate. The obtained polymers exhibited superior thermal properties compared to the precursor polymers owing to the rigid cage structures of TEAB. The pendant TEAB groups were relatively stable to hydrolysis, but were quantitatively hydrolyzed in the presence of fluoride anions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据