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Visible Light-Induced Transition Metal Catalysis

CHEMICAL REVIEWS (2022)

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Article Chemistry, Multidisciplinary

Visible Light Induced Bifunctional Rhodium Catalysis for Decarbonylative Coupling of Imides with Alkynes

Xiang-Ting Min et al.

Summary: Transition metal catalyzed decarbonylation offers a unique synthetic strategy for new chemical bond formation. The study developed a visible light induced rhodium catalysis for decarbonylative coupling of imides with alkynes under ambient conditions, revealing the rhodium complex serves as both the catalytic center and photosensitizer. This visible light promoted catalytic decarbonylation strategy opens up new opportunities for re-evaluating old transformations with ligand dissociation as a rate-determining step.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Light-Promoted Copper-Catalyzed Enantioselective Alkylation of Azoles

Chen Li et al.

Summary: A catalytic asymmetric alkylation of azoles with secondary 1-arylalkyl bromides through direct C-H functionalization was reported. The reaction, under blue-light photoexcitation, showed good reactivity and high stereoselectivity, providing an efficient strategy for the construction of chiral alkyl azoles at low temperature. The reactions are compatible with a wide range of azoles.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Light-Promoted C-N Coupling of Aryl Halides with Nitroarenes

Gang Li et al.

Summary: This study demonstrates a photochemical C-N coupling of aryl halides with nitroarenes for the first time, catalyzed by a Ni-II complex in the absence of any external photosensitizer. The method provides a step-economic extension to the widely used Buchwald-Hartwig C-N coupling reaction and tolerates coupling partners with steric-congestion and functional groups sensitive to bases and nucleophiles. Mechanistic studies suggest the reaction proceeds via the addition of an aryl radical, generated from a Ni-I/Ni-III cycle, to a nitrosoarene intermediate.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Multidisciplinary

Light in Gold Catalysis

Sina Witzel et al.

Summary: Gold photocatalysis in gold-catalyzed reactions offers unique advantages, allowing for valence change of the gold center through electron transfer and radical addition without the need for stoichiometric sacrificial oxidants. The compatibility of radicals with gold catalysts enables a variety of important organic transformations, including redox-neutral C-C and C-X coupling, C-H activation, and formal radical-radical cross-coupling.

CHEMICAL REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Photoinduced Palladium-Catalyzed Dicarbofunctionalization of Terminal Alkynes

Zhen Yang et al.

Summary: A conceptually distinct approach was developed for the dicarbofunctionalization of alkynes at room temperature using simple alkyl iodides and a second molecule of alkyne as coupling partner. This method enables the one-step synthesis of 1,3-enynes with high efficiency without the need for exogenous photosensitizers or oxidants, paving the way for cascade reactions via photochemical palladium catalysis.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Excited-State Palladium-Catalyzed 1,2-Spin-Center Shift Enables Selective C-2 Reduction, Deuteration, and Iodination of Carbohydrates

Gaoyuan Zhao et al.

Summary: The study presents the first excited-state palladium-catalyzed 1,2-spin-center shift reaction for site-selective functionalization of carbohydrates. The strategy offers mild reaction conditions with high levels of selectivity, tolerating a wide range of functional groups and complex molecular architectures, suggesting a general approach for the rapid generation of natural and unnatural carbohydrates.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Organic

Manganese-Catalyzed N-F Bond Activation for Hydroamination and Carboamination of Alkenes

Yun-Xing Ji et al.

Summary: This study presents a visible-light-promoted method for generating amidyl radicals from N-fluorosulfonamides via a manganese-catalyzed N-F bond activation strategy, using a simple manganese complex and a cheap silane as reactants. This method enables the intramolecular/intermolecular hydroaminations of alkenes, two-component carboamination of alkenes, and even three-component carboamination of alkenes, allowing for the preparation of a wide range of valuable aliphatic sulfonamides.

ORGANIC LETTERS (2021)

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Article Chemistry, Organic

Vitamin B12-Catalyzed Dicarbofunctionalization of Bromoalkenes Under Visible Light Irradiation

Sabina Smolen et al.

Summary: Vitamin B-12 plays a crucial role as a catalyst in organic reactions, facilitating the dicarbofuntionalization of bromoalkenes with electrophilic olefins to yield substituted pyrrolidines and piperidines efficiently.

SYNTHESIS-STUTTGART (2021)

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Review Chemistry, Multidisciplinary

Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp3)-H Cross-Coupling

Stavros K. Kariofillis et al.

Summary: In recent years, the development of light-driven reactions has made significant advancements in synthetic organic chemistry, particularly in combining photoredox and nickel catalysis for challenging cross-coupling reactions. The question of whether photo-induced activation of the nickel catalyst itself could lead to new approaches to cross-coupling has been explored. By utilizing a visible-light-driven mechanism for chlorine radical formation and conducting mechanistic investigations on organometallic Ni complexes relevant to cross-coupling, the study aims to facilitate new catalyst design and develop novel synthetic methods.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

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Review Chemistry, Multidisciplinary

Visible-Light-Induced Homolysis of Earth-Abundant Metal-Substrate Complexes: A Complementary Activation Strategy in Photoredox Catalysis

Youssef Abderrazak et al.

Summary: The mainstream applications of visible-light photoredox catalysis mainly involve precious metal Ru-II or Ir-III complexes or organic dyes with low photostability. Earth-abundant metal-based (MLn)-L-n-type complexes are evolving rapidly as alternative photocatalysts that offer economic and ecological advantages and access to complementary inner-sphere mechanistic modes, transcending the inherent limitations of ultrashort excited-state lifetimes. The process of visible-light-induced homolysis (VLIH) involves the formation of light-absorbing ligated metal-substrate complexes that undergo homolytic cleavage for further transformations.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Multidisciplinary

Late-Stage Alkylation of Heterocycles Using N-(Acyloxy)phthalimides

Sushanta Kumar Parida et al.

Summary: Synthetic methods enabling late-stage modification of heterocycles are crucial in the pharmaceutical and agrochemical industry. The development of catalysts has made C-H alkylation of heterocycles more accessible and efficient, leading to significant breakthroughs in medicinal chemistry.

CHEMISTRY-AN ASIAN JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Copper Catalyzed C(sp3)- H Bond Alkylation via Photoinduced Ligand-to-Metal Charge Transfer

Sean M. Treacy et al.

Summary: By utilizing catalytic CuCl2, various feedstock chemicals can be functionalized through the coupling of unactivated C(sp(3))-H bonds with electron-deficient olefins. This reaction, enabled by Ligand-to-Metal Charge Transfer (LMCT), generates a chlorine radical capable of abstracting strong electron-rich C(sp(3))-H bonds. The protocol offers a simple operation and atom economical approach to generate a highly active hydrogen atom transfer reagent.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Organic

Visible-Light Decatungstate/Disulfide Dual Catalysis for the HydroFunctionalization of Styrenes

Alexis Prieto et al.

Summary: An efficient photoredox system based on decatungstate/disulfide catalysts was developed for the hydrofunctionalization of styrenes. The use of disulfide as a cocatalyst was crucial for enhancing reaction efficiency, allowing for the synthesis of a wide variety of useful building blocks and high-value molecules from simple starting materials, such as amides and unsymmetrical ketones.

ORGANIC LETTERS (2021)

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Article Chemistry, Organic

Synthesis of Unnatural α-Amino Acids via Photoinduced Decatungstate-Catalyzed Giese Reactions of Aldehydes

Xinmou Wang et al.

Summary: The study introduces an efficient and general method for synthesizing gamma-carbonyl alpha-amino acids through photoinduced decatungstate-catalyzed Giese reactions of readily available aldehydes as radical precursors. The mild and robust method is compatible with a wide array of functional groups and has a broad substrate scope. The utility of the method was demonstrated by modifying several amino acid bearing drugs and natural products.

ORGANIC LETTERS (2021)

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Article Multidisciplinary Sciences

Pd-catalyzed formal Mizoroki-Heck coupling of unactivated alkyl chlorides

Geun Seok Lee et al.

Summary: The use of alkyl chlorides in Pd-catalyzed Mizoroki-Heck coupling reactions remains a challenging issue due to the high thermodynamic barrier of alkyl chloride activation and the propensity of alkylpalladium complexes to undergo undesired beta-hydride elimination. However, this study demonstrates that alkyl chlorides, including tertiary ones, can efficiently participate in Mizoroki-Heck cross-coupling reactions under mild conditions via photoinduced Pd catalysis, offering great potential for late-stage functionalizations and molecular complexity.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Physical

Visible Light-Induced Pd-Catalyzed Alkyl-Heck Reaction of Oximes

Nikita Kvasovs et al.

Summary: This method utilizes visible light-induced generation of nucleophilic hybrid alkyl Pd radical intermediates to achieve efficient atom economical C-C bond construction of alkyl-substituted oximes, allowing a broad range of primary, secondary, and tertiary alkyl bromides and iodides, as well as a range of different formaldoximes, to efficiently undergo this transformation.

ACS CATALYSIS (2021)

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Review Chemistry, Applied

Visible-Light-Induced Manganese-Catalyzed Reactions: Present Approach and Future Prospects

Ramen Jamatia et al.

Summary: Manganese as a novel visible-light-induced catalyst shows great promise in terms of economic sustainability and applicability, leading to significant advancements in organic, polymer, and materials chemistry fields in recent years. Through manganese-catalyzed reactions, late-stage functionalization of valuable compounds and natural products can be realized, which is important for the development of medicinal and pharmaceutical chemistry.

ADVANCED SYNTHESIS & CATALYSIS (2021)

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Article Chemistry, Multidisciplinary

Radical Decarboxylative Carbometalation of Benzoic Acids: A Solution to Aromatic Decarboxylative Fluorination

Peng Xu et al.

Summary: A variety of aromatic carboxylic acids exist in nature and are synthesized through different methods. The decarboxylative functionalization of benzoic acids is mainly achieved through transition-metal-catalyzed decarboxylative cross couplings. However, the high activation barrier for thermal decarboxylative carbometalation limits the scope of suitable reactions. This study presents a new approach with a low-barrier photoinduced ligand to metal charge transfer to enable radical decarboxylative carbometalation, allowing for previously unrealized general decarboxylative fluorination of benzoic acids.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Organic

Asymmetric Photocatalytic C(sp3)-H Bond Addition to α-Substituted Acrylates

Zhen-Yao Dai et al.

Summary: The asymmetric functionalization of inert C(sp(3))-H bonds was achieved using a photocatalytic method with TBADT and chiral phosphoric acid, allowing rapid synthesis of enantioenriched astereogenic esters from simple raw materials.

ORGANIC LETTERS (2021)

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Article Chemistry, Organic

Decatungstate as Direct Hydrogen Atom Transfer Photocatalyst for SOMOphilic Alkynylation

Luca Capaldo et al.

Summary: A versatile approach for alkynylation of various aliphatic hydrogen donors including alkanes was achieved using tetrabutylammonium decatungstate as a photocatalyst. The reaction mechanism involved generating organoradicals from C-H/Si-H bonds followed by SOMOphilic alkynylation to form internal alkynes. The impact of different radicofugal groups on the reaction outcome was evaluated through experimental and computational methods.

ORGANIC LETTERS (2021)

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Article Chemistry, Multidisciplinary

Photo-induced copper-catalyzed alkynylation and amination of remote unactivated C(sp3)-H bonds

Zhusong Cao et al.

Summary: The method involves the use of a copper nucleophile complex as a photocatalyst, which reduces the silicon-tethered aliphatic iodide to an alkyl radical to initiate 1,n-hydrogen atom transfer. Unactivated secondary and tertiary C-H bonds at beta, gamma, and delta positions can be functionalized in a predictable manner.

CHEMICAL SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Three-component three-bond forming cascade via palladium photoredox catalysis

Peter Bellotti et al.

Summary: A highly modular radical cascade strategy based on radical cyclisation/allylic substitution sequence has been described, achieving efficient synthesis between alkyl/aryl bromides, 1,3-dienes, and various nucleophiles. Palladium phosphine complexes play a crucial role in this reaction, enabling 1,4-selectivity and stereocontrol to deliver carbocyclic and heterocyclic structures with important functional groups. Additionally, a flow chemistry approach was applied for the first time in palladium-photocatalysed endeavors involving radicals.

CHEMICAL SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Visible-light-driven palladium-catalyzed Dowd-Beckwith ring expansion/C-C bond formation cascade

Li Chen et al.

Summary: A visible light-induced palladium-catalyzed Dowd-Beckwith ring expansion/C-C bond formation cascade has been successfully developed to access a variety of six to nine-membered beta-alkenylated cyclic ketones with a quaternary carbon center under mild conditions. In addition to styrenes, electron-rich alkenes like silyl enol ethers and enamides are also compatible substrates, providing the desired beta-alkylated cyclic ketones in moderate to good yields.

CHEMICAL SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt

Kimihiro Komeyama et al.

Summary: The scope of the Giese reaction is expanded using readily available alkyl tosylates as substrates and nucleophilic cobalt(i) catalysts under visible-light irradiation, preferentially with less bulky primary alkyl tosylates. This unique reactivity enables the regio-selective Giese reaction of polyol derivatives.

RSC ADVANCES (2021)

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Article Chemistry, Organic

Making Copper Photocatalysis Even More Robust and Economic: Photoredox Catalysis with [CuII(dmp)2Cl]Cl

Sebastian Engl et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2020)

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Article Chemistry, Organic

Vitamin B12 Enables Consecutive Generation of Acyl and Alkyl Radicals from One Reagent

Aleksandra Potrzasaj et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Synthesis of All-Carbon Quaternary Centers by Palladium-Catalyzed Olefin Dicarbofunctionalization

Maximilian Koy et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Generation and Reactivity of Amidyl Radicals: Manganese-Mediated Atom-Transfer Reaction

Run-Zhou Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Energy Transfer from CdS QDs to a Photogenerated Pd Complex Enhances the Rate and Selectivity of a Pd-Photocatalyzed Heck Reaction

Zhengyi Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Organic

Copper-Catalyzed Photoinduced Enantioselective Dual Carbofunctionalization of Alkenes

Yajing Zhang et al.

ORGANIC LETTERS (2020)

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Article Chemistry, Organic

Intramolecular Aromatic C-H Acyloxylation Enabled by Iron Photocatalysis

Siqi Xia et al.

ORGANIC LETTERS (2020)

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Article Chemistry, Physical

Palladium-Catalyzed Dual Ligand-Enabled Alkylation of Silyl Enol Ether and Enamide under Irradiation: Scope, Mechanism, and Theoretical Elucidation of Hybrid Alkyl Pd(I)-Radical Species

Bin Zhao et al.

ACS CATALYSIS (2020)

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Article Chemistry, Multidisciplinary

Visible-Light-Induced Palladium-Catalyzed Generation of Aryl Radicals from Aryl Triflates

Maxim Ratushnyy et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Light-Promoted Nickel Catalysis: Etherification of Aryl Electrophiles with Alcohols Catalyzed by a NiII-Aryl Complex

Liu Yang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Biochemistry & Molecular Biology

Emerging strategies for expanding the toolbox of enzymes in biocatalysis

Braddock A. Sandoval et al.

CURRENT OPINION IN CHEMICAL BIOLOGY (2020)

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Adual light-driven palladium catalyst: Breaking the barriers incarbonylation reactions

Gerardo M. Torres et al.

SCIENCE (2020)

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Article Chemistry, Physical

Light-Mediated Asymmetric Aliphatic C-H Alkylation with Hydrogen Atom Transfer Catalyst and Chiral Phosphoric Acid

Zhen-Yao Dai et al.

ACS CATALYSIS (2020)

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Polarity-Reversal Strategy for the Functionalization of Electrophilic Strained Molecules via Light-Driven Cobalt Catalysis

Michal Ociepa et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Photoinduced Palladium-Catalyzed Carbofunctionalization of Conjugated Dienes Proceeding via Radical-Polar Crossover Scenario: 1,2-Aminoalkylation and Beyond

Kelvin Pak Shing Cheung et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Three-Component, Interrupted Radical Heck/Allylic Substitution Cascade Involving Unactivated Alkyl Bromides

Huan-Ming Huang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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3d-d Excited States of Ni(II) Complexes Relevant to Photoredox Catalysis: Spectroscopic Identification and Mechanistic Implications

Stephen Ting et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Review Chemistry, Physical

Palladium and Copper Catalyzed Sonogashira cross Coupling an Excellent Methodology for C-C Bond Formation over 17 Years: A Review

Iram Kanwal et al.

CATALYSTS (2020)

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Catalytic radical generation of π-allylpalladium complexes

Huan-Ming Huang et al.

NATURE CATALYSIS (2020)

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Article Chemistry, Organic

Visible-Light-Induced Palladium-Catalyzed Intermolecular Narasaka-Heck Reaction at Room Temperature

Liyan Feng et al.

ORGANIC LETTERS (2020)

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Photoinduced Copper-Catalyzed Asymmetric Decarboxylative Alkynylation with Terminal Alkynes

Hai-Dong Xia et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Light Runs Across Iron Catalysts in Organic Transformations

Wen-Jun Zhou et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

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Visible Light-Induced Copper-Catalyzed C-H Arylation of Benzoxazoles

Xiaodong Ma et al.

CHINESE JOURNAL OF CHEMISTRY (2020)

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Visible-Light-Induced Palladium-Catalyzed Carbocyclization of Unactivated Alkyl Bromides with Alkenes Involving C-I or C-B Coupling

Jun-Wei Ma et al.

JOURNAL OF ORGANIC CHEMISTRY (2020)

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Direct Evidence of Visible Light-Induced Homolysis in Chlorobis(2,9-dimethyl-1,10-phenanthroline)copper(II)

Remi Fayad et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

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Visible-Light-Induced Vicinal Dichlorination of Alkenes through LMCT Excitation of CuCl2

Pengcheng Lian et al.

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Cobaloxime Catalysis for Enamine Phosphorylation with Hydrogen Evolution

Tao Lei et al.

ORGANIC LETTERS (2020)

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Visible-Light-Induced Pd-Catalyzed Radical Strategy for Constructing C-Vinyl Glycosides

Ming Li et al.

ORGANIC LETTERS (2020)

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C(sp3)-H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow

Gabriele Laudadio et al.

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Review Chemistry, Physical

Transition Metal-Catalyzed Organic Reactions under Visible Light: Recent Developments and Future Perspectives

Wan-Min Cheng et al.

ACS CATALYSIS (2020)

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Copper Makes the Difference: Visible Light-Mediated Atom Transfer Radical Addition Reactions of Iodoform with Olefins

Sebastian Engl et al.

ACS CATALYSIS (2020)

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Article Chemistry, Organic

Visible-Light-Accelerated Pd-Catalyzed Cascade Addition/Cyclization of Arylboronic Acids to γ- and β-Ketodinitriles for the Construction of 3-Cyanopyridines and 3-Cyanopyrrole Analogues

Amitava Rakshit et al.

JOURNAL OF ORGANIC CHEMISTRY (2020)

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Article Chemistry, Organic

Photocatalytic Palladium-Catalyzed Fluoroalkylation of Styrene Derivatives

Reka Adamik et al.

ORGANIC LETTERS (2020)

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Direct C(sp2)-H alkylation of unactivated arenes enabled by photoinduced Pd catalysis

Daeun Kim et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Physical

Photocatalytic Generation of Aminium Radical Cations for C-N Bond Formation

Jacob M. Ganley et al.

ACS CATALYSIS (2020)

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Article Chemistry, Multidisciplinary

C-H functionalization reactions enabled by hydrogen atom transfer to carbon-centered radicals

Sumon Sarkar et al.

CHEMICAL SCIENCE (2020)

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Article Chemistry, Organic

Decarboxylative C-H Alkylation of Heteroarene N-Oxides by Visible Light/Copper Catalysis

Duan-Yang Liu et al.

ORGANIC LETTERS (2020)

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Article Chemistry, Organic

Tertiary Amines Acting as Alkyl Radical Equivalents Enabled by a P/N Heteroleptic Cu(I) Photosensitizer

Limeng Zheng et al.

ORGANIC LETTERS (2020)

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Formyl-selective deuteration of aldehydes with D2O via synergistic organic and photoredox catalysis

Jianyang Dong et al.

CHEMICAL SCIENCE (2020)

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Visible light driven deuteration of formyl C-H and hydridic C(sp3)-H bonds in feedstock chemicals and pharmaceutical molecules

Yulong Kuang et al.

CHEMICAL SCIENCE (2020)

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Article Chemistry, Organic

Mn-Catalysed photoredox hydroxytrifluoromethylation of aliphatic alkenes using CF3SO2Na

Wenhao Long et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2020)

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Three-component aminoselenation of alkenes via visible-light enabled Fe-catalysis

Binbin Huang et al.

GREEN CHEMISTRY (2020)

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Ortho C-H arylation of arenes at room temperature using visible light ruthenium C-H activation

Arunachalam Sagadevan et al.

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Visible light-induced aerobic oxidation of diarylalkynes to α-diketones catalyzed by copper-superoxo at room temperature

Vaibhav Pramod Charpe et al.

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Visible-light-mediated borylation of aryl and alkyl halides with a palladium complex

Jia-Hui Zhao et al.

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Photoexcited Pd(ii) auxiliaries enable light-induced control in C(sp3)-H bond functionalisation

Milena L. Czyz et al.

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Visible light-promoted copper catalyzed regioselective acetamidation of terminal alkynes by arylamines

V. Kishore Kumar Pampana et al.

GREEN CHEMISTRY (2020)

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Review Chemistry, Multidisciplinary

First-Row Transition-Metal-Catalyzed Carbonylative Transformations of Carbon Electrophiles

Jin-Bao Peng et al.

CHEMICAL REVIEWS (2019)

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Open-Air Alkylation Reactions in Photoredox-Catalyzed DNA-Encoded Library Synthesis

James P. Phelan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Copper-Catalyzed Intermolecular Carboamination of Alkenes Induced by Visible Light

Yang Xiong et al.

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Anionic Cyclometalated Platinum(II) Tetrazolato Complexes as Viable Photoredox Catalysts

Anna Maria Ranieri et al.

ORGANOMETALLICS (2019)

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Visible-Light-Enabled Ruthenium-Catalyzed meta-C-H Alkylation at Room Temperature

Parthasarathy Gandeepan et al.

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meta-Selective C-H Activation of Arenes at Room Temperature Using Visible Light: Dual-Function Ruthenium Catalysis

Arunachalam Sagadevan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Review Chemistry, Multidisciplinary

Organocobalt Complexes as Sources of Carbon-Centered Radicals for Organic and Polymer Chemistries

Jeremy Demarteau et al.

CHEMICAL REVIEWS (2019)

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Article Chemistry, Multidisciplinary

Transition-Metal- and Light-Free Directed Amination of Remote Unactivated C(sp3)-H Bonds of Alcohols

Daria Kurandina et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Organic

Radical Addition to N-Tosylimines via C-H Activation Induced by Decatungstate Photocatalyst

Vyacheslav I. Supranovich et al.

ORGANIC LETTERS (2019)

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Article Chemistry, Organic

Visible-Light-Initiated Manganese-Catalyzed E-Selective Hydrosilylation and Hydrogermylation of Alkynes

Hao Liang et al.

ORGANIC LETTERS (2019)

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Article Chemistry, Organic

Gram-Scale, Cheap, and Eco-Friendly Iron-Catalyzed Cross-Coupling between Alkyl Grignard Reagents and Alkenyl or Aryl Halides

Gerard Cahiez et al.

ORGANIC LETTERS (2019)

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Copper-catalyzed oxidative alkyne homocoupling without palladium, ligands and bases

Xueshun Jia et al.

GREEN CHEMISTRY (2011)

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CuCl-catalyzed green oxidative alkyne homocoupling without palladium, ligands and bases

Kun Yin et al.

GREEN CHEMISTRY (2011)

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Estimation of Standard Reduction Potentials of Halogen Atoms and Alkyl Halides

Abdirisak A. Isse et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2011)

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Room-Temperature C-H Arylation: Merger of Pd-Catalyzed C-H Functionalization and Visible-Light Photocatalysis

Dipannita Kalyani et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

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Vicinal C-Functionalization of Alkenes. Pd/Light-Induced Multicomponent Coupling Reactions Leading to Functionalized Esters and Lactones

Akira Fusano et al.

ORGANIC LETTERS (2011)

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Investigating the Rate of Photoreductive Glucosyl Radical Generation

R. Stephen Andrews et al.

ORGANIC LETTERS (2011)

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Copper(I) Iodide Catalyzed Cross-Coupling Reaction of Terminal Alkynes with 1-Bromoalkynes: A Simple Synthesis of Unsymmetrical Buta-1,3-diynes

Shihua Wang et al.

SYNTHESIS-STUTTGART (2011)

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Intermolecular Addition of Glycosyl Halides to Alkenes Mediated by Visible Light

R. Stephen Andrews et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

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Review Chemistry, Multidisciplinary

Palladium-Catalyzed Ligand-Directed C-H Functionalization Reactions

Thomas W. Lyons et al.

CHEMICAL REVIEWS (2010)

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Sub-Mol % Catalyst Loading and Ligand-Acceleration in the Copper-Catalyzed Coupling of Aryl Iodides and Terminal Alkyenes

Erik Zuidema et al.

CHEMISTRY-A EUROPEAN JOURNAL (2010)

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Enantioselective α-Benzylation of Aldehydes via Photoredox Organocatalysis

Hui-Wen Shih et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

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Palladium-Catalyzed Carbonylative Heck-Type Reactions of Alkyl Iodides

Kayla S. Bloome et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

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Article Chemistry, Organic

Synthesis of Alkyl Alkynyl Ketones by Pd/Light-Induced Three-Component Coupling Reactions of Iodoalkanes, CO, and 1-Alkynes

Akira Fusano et al.

ORGANIC LETTERS (2010)

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Radical Catalysis of Kumada Cross-Coupling Reactions Using Functionalized Grignard Reagents

Georg Manolikakes et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

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Review Chemistry, Multidisciplinary

Palladium(II)-Catalyzed C-H Activation/C-C Cross-Coupling Reactions: Versatility and Practicality

Xiao Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

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Solar light-driven photocatalyzed alkylations. Chemistry on the window ledge

Stefano Protti et al.

CHEMICAL COMMUNICATIONS (2009)

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Decatungstate as an efficient photocatalyst in organic chemistry

Manolis D. Tzirakis et al.

CHEMICAL SOCIETY REVIEWS (2009)

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Review Chemistry, Multidisciplinary

Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides

Takuji Hatakeyama et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

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Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis

David A. Nagib et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

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Nickel-Catalyzed Oxidative Coupling Reactions of Two Different Terminal Alkynes Using O2 as the Oxidant at Room Temperature: Facile Syntheses of Unsymmetric 1,3-Diynes

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ORGANIC LETTERS (2009)

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Review Chemistry, Multidisciplinary

Metal-catalyzed enantioselective allylation in asymmetric synthesis

Zhan Lu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

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Recent progress in the generation and use of nitrogen-centred radicals

Samir Z. Zard

CHEMICAL SOCIETY REVIEWS (2008)

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Investigation of an Efficient Palladium-Catalyzed C(sp)-C(sp) Cross-Coupling Reaction Using Phosphine-Olefin Ligand: Application and Mechanistic Aspects

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SCIENCE (2008)

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Homogeneous catalysis of platinum(II) complexes in photochemical hydrogen production from water

Ken Sakai et al.

COORDINATION CHEMISTRY REVIEWS (2007)

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Intramolecular Heck reactions of unactivated alkyl halides

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

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Atom transfer carbonylation using ionic liquids as reaction media

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Effective acceleration of atom transfer carbonylation of alkyl iodides by metal complexes. Application to the synthesis of the hinokinin precursor and dihydrocapsaicin

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ORGANIC LETTERS (2006)

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Review Chemistry, Multidisciplinary

Catalysts for cross-coupling reactions with non-activated alkyl halides

AC Frisch et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)

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Photocatalytic hydrogen production from hantzsch 1,4-dihydropyridines by platinum(II) terpyridyl complexes in homogeneous solution

D Zhang et al.

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Photocatalytic oxidation of alkanes with dioxygen by visible light and copper(II) and iron(III) chlorides: Preference oxidation of alkanes over alcohols and ketones

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Carbon-carbon bond construction based on radical addition to C=N bond

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Converting carbon dioxide into carbamato derivatives

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ACCOUNTS OF CHEMICAL RESEARCH (2003)

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Oxidation of alkanes with dioxygen induced by visible light and Cu(II) and Fe(III) chlorides

K Takaki et al.

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN (2003)

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Cascade radical reactions catalyzed by a Pd/light system: Cyclizative multiple carbonylation of 4-alkenyl iodides

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Review Chemistry, Organic

Addition of carbon-centered radicals to imines and related compounds

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TETRAHEDRON (2001)

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Article Chemistry, Organic

Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide α-arylation.: Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations

S Lee et al.

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Femtosecond excited-state dynamics of an iron(II) polypyridyl solar cell sensitizer model

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