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Development of Methods to the Synthesis of β-Boryl Acyls, Imines and Nitriles

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CHEMICAL RECORD
卷 22, 期 4, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.202100290

关键词

organoboron compounds; acemic synthesis; asymmetric synthesis; beta-borylation; transition metals

资金

  1. DST [CRG/2020/001892]
  2. IIT Kharagpur
  3. CSIR

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Organoboron compounds are important and versatile synthetic intermediates in the preparation of organic molecules. Among all organoboron compounds, beta-boryl carbonyl compounds have emerged as promising intermediates for various synthetic transformations. This mini-review provides an overview of the numerous racemic and asymmetric beta-borylation methods developed to date.
Organoboron compounds are highly important and versatile synthetic intermediates for the preparation of a wide range of organic molecules. Organoboron compounds have drawn significant attention among organic chemists due to their Lewis acidic property, non-toxicity, and commercial availability. Over the last several decades, there has been a substantial development of new organoboron compounds, useful in organic synthesis. Among all other organoboron compounds, beta-boryl carbonyl compounds are the important ones. The beta-boryl compounds have appeared as promising intermediates for various synthetic transformations. The 1,4-conjugate addition of diboron reagents to carbon-carbon double bond in the presence of different transition-metal catalysts has been extensively reported by various research groups across the globe. This mini-review outlines the numerous racemic as well as asymmetric beta-borylation methods developed to date.

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