期刊
CHEMICAL ENGINEERING JOURNAL
卷 430, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2021.132743
关键词
Zn negative electrode; Corrosion resistance; Voltage hysteresis; Dual-ion battery; Cycling stability
资金
- National Natural Science Foundation of China [51874019, 51804022]
- Fundamental Research Funds for the Central Universities [FRF-TP-17-002C2]
This study demonstrates that zinc is a promising negative electrode with corrosion resistance, low voltage hysteresis, and stability. Zinc electrode shows good structural integrity, cycling stability, and corrosion resistance in Al dual-ion batteries, making it a viable alternative option for high stability negative electrodes.
Compared with the widely developed positive electrodes, the research on the high stability negative electrodes is far from in-depth in nonaqueous Al batteries. In order to fundamentally solve these key problems, including Al dendrites, corrosion and pulverization, it is urgent to develop an alternative stable negative electrode. Herein, the corrosion-resistant, low-voltage-hysteresis and stable Zn is demonstrated as a promising negative electrode. Since the deposited Al particles on the Zn electrode are prior to Zn in the stripping reaction, Zn electrode can remain good structural integrality, thus presenting great cycling stability and corrosion resistance. Importantly, the results in Al-Zn symmetric cells indicate that Zn possesses the ultra-low voltage hysteresis (-17 mV at 0.5 mA cm-2), superior cycling stability (800 cycles at 1.0 mA cm-2) and Al plating/stripping reversibility characteristics. Additionally, the Zn-graphite full battery based on Zn as negative electrode and flake graphite as positive electrode delivers stable discharge capacity of 81.1 mAh g-1 over 300 cycles. The results in this work open an effective approach for constructing corrosion-resistant, low-voltage-hysteresis and stable negative electrode, further indicating that Zn is great promising as negative electrode for Al dual-ion batteries.
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