期刊
CHEMICAL ENGINEERING JOURNAL
卷 428, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2021.132003
关键词
Cr3+-doped phosphor; NIR pc-LED; Photomorphogenesis; Plant growth
资金
- National Natural Science Foundations of China [21671070, 51802101]
- Guangdong Basic and Applied Basic Research Foundation [2021A1515012613]
- Guangdong Provincial Science & Technology Project [2020A1414010046, 2021A0505050006]
- Guangzhou Science & Technology Project [202007020005]
- Natural Science Foundation of Guangdong Province [2018A030310217]
- Project of GDUPS (2018)
- Guangdong Provincial Special Fund for Modern Agriculture Industry Technology Innovation Teams [2021KJ131, 2021KJ122]
A novel near-infrared phosphor, GLGA:Cr3+, was developed with excellent optical performance for regulating photomorphogenesis of plants. A phosphor-converted LED with high photoelectric conversion efficiency was fabricated, demonstrating enhanced biomass of pea seedlings under supplementary near-infrared light irradiation. This research opens up avenues for further investigation into Cr3+ -doped near-infrared phosphors for plant photomorphogenesis regulation.
Far-red/phytochmme (P-FR) plays a key role in photomorphogenesis of plants. However, how to obtain a near-infrared (NIR) emitting phosphor with high external quantum efficiency (EQE), suitable spectral profile, and low thermal quenching remains a huge challenge. Herein, a NIR phosphor, Gd2.4Lu0.6Ga4AlO12:Cr3+,H3BO3 (GLGA:Cr3+) was developed via regulating the crystal field environment and adding fluxes, which exhibits a peak maximum at 728 nm with a relatively narrow full-width at half maximum (FWHM) of 107 nm, matching well with the absorption band of P-FR. Upon 450 nm excitation, the internal quantum efficiency (IQE) and EQE of the optimal phosphor are 90.3% and 32.0%, respectively. At 423 K, the integrated emission intensity of the investigated phosphor is about 75% of that at room temperature. Benefiting from the excellent optical performance, a NIR phosphor-converted light-emitting diode (pc-LED) was fabricated, which shows a NIR output power of 505.99 mW and photoelectric conversion efficiency of 11.24% at 300 mA. Moreover, plant growth experiments demonstrate that the biomass of pea seedlings is increased by 67.72% under supplementary NIR light irradiation. The findings of this research will motivate further research on new Cr3+ -doped NIR phosphors for regulating photomorphogenesis of plants.
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