☆ 4.7 Article

Non-kinetic phenomena in thermal analysis data; Computational fluid dynamics reactor studies

CHEMICAL ENGINEERING JOURNAL (2021)

Selection of Formal Baseline Correction Methods in Thermal Analysis

Rebecca L. Gibson et al.

Summary: Baseline correction is a crucial step in thermal analysis data processing, and the selection of the correct correction method can significantly impact the parameters obtained from kinetic modeling. Linear correction methods should be prioritized, and the choice of correction method should be based on comparison of Akaike weights.

CHEMICAL ENGINEERING & TECHNOLOGY (2022)

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Article Engineering, Environmental

Kinetic modelling of thermal processes using a modified Sestak-Berggren equation

Rebecca L. Gibson et al.

Summary: This study outlines a methodology for modeling the kinetics of solid-state reactions through the modified Sestak-Berggren equation, demonstrating its internal consistency, applicability to noisy data, and ability to predict mechanisms occurring during thermally induced solid state reactions. It recommends a statistical approach based on the Akaike Information Criteria to determine the optimal number of thermal events for a system, and provides recommendations for handling datasets containing closely overlapped peaks.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Energy & Fuels