期刊
CHEMICAL ENGINEERING JOURNAL
卷 430, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2021.132821
关键词
Electrochromic; Capacitive; Balanced; Repairable; Ion trap
资金
- National Natural Science Foundation of China [51772023, 51572020]
The TiO2/WO3 nanorod composite material exhibits balanced electrochromic and capacitive properties, with excellent coloration efficiency, fast color switching response, and high capacitance. A new concept of stability in industrial sense was introduced, and a theoretical model was used to explain the decline in material stability during cycles.
Electrochromic-capacitive bifunctional materials have been widely developed in recent years due to their broad application prospects. However, the failure to achieve all-round excellent performance simultaneously, as well as the limited stability restricted their large-scale commercialization. Here, we prepared a TiO2/WO3 nanorod composite material, which showed balanced electrochromic and capacitive properties without any significant shortcoming in all aspects. Generally, the material possessed excellent coloration efficiency (153.1 cm(2) C-1), fast color switching response (10/10s) and high capacitance (557.7 F g(-1) at 1 A g(-1)). In addition, a new concept of stability in industrial sense was firstly proposed to redefining the durability of materials. The decline of material stability during cycles was fully explained by a theoretical model of ion trap, which contained two categories: (1) eliminable trap and (2) non-eliminable trap. The eliminable trap could be removed by a detrapping treatment, so that all the properties of declined materials could be restored, while the non-eliminable trap couldn't be removed.
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