4.7 Article

Recent advances in electrocatalytic nitrite reduction

期刊

CHEMICAL COMMUNICATIONS
卷 58, 期 17, 页码 2777-2787

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc06690k

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资金

  1. National Natural Science Foundation of China [22101202, 22071173]
  2. China National Postdoctoral Program for Innovative Talents [2021M702436]
  3. Natural Science Foundation of Tianjin City [20JCJQJC00050]

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This review highlights the recent progress and applications of electrochemical nitrite reduction, including the preparation of gaseous and liquid products, catalyst selection, and understanding of reaction mechanisms. The challenges and opportunities in this field are analyzed as well.
Electrocatalytic nitrite reduction is of great significance for wastewater treatment and value-added chemicals synthesis. This review highlights the latest progress in electrochemical nitrite reduction to produce two types of products, including gaseous products (NO, N2O, N-2) and liquid products (NH2OH and NH4+). The heterogeneous and homogeneous catalysts used in the corresponding reduction processes are introduced, with emphasis on the product selectivity regulation and reaction mechanism understanding. Finally, the challenges and opportunities in this field are analyzed as well. This review can provide guidelines for designing electrochemical systems with high efficiency and specificity for nitrite reduction.

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