期刊
CHEMICAL COMMUNICATIONS
卷 58, 期 2, 页码 270-273出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc06361h
关键词
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资金
- National Natural Science Foundation of China [81773602, 21901049, 21801032]
- Guangdong Special Support Program [2017TQ04R599]
- Natural Science Foundation of Chongqing [cstc2019jcyj-msxmX0138]
- Youth Innovation Promotion Association of CAS [2020342]
- Guangxi Natural Science Foundation [2018GXNSFBA050015, AD19245004]
- Guangxi University for Nationalities' Scientific Research Funds for Talent Introduction [2018KJQD09]
- Foundation of Key Laboratory of Plant Resources Conservation and Sustainable Utilization, South China Botanical Garden, Chinese Academy of Sciences
Driven by bioinspiration and appreciation of the structure of ericifolione, a biomimetic tautomerization/intermolecular inverse-electron-demand hetero Diels-Alder reaction cascade sequence promoted by sodium acetate to rapidly construct sterically hindered dihydropyran scaffolds was established, allowing the first straightforward biomimetic total syntheses of ericifolione and its analogues with high simplicity. Moreover, this methodology set the stage for the preparation of relevant natural products or derivatives.
Driven by bioinspiration and appreciation of the structure of ericifolione, a biomimetic tautomerization/intermolecular inverse-electron-demand hetero Diels-Alder reaction cascade sequence promoted by sodium acetate to rapidly construct sterically hindered dihydropyran scaffolds was established, which allowed the first straightforward biomimetic total syntheses of ericifolione and its analogues with high simplicity. Moreover, this methodology set the stage for the preparation of relevant natural products or derivatives.
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