4.7 Article

On the origin of chaotrope-modulated electrocatalytic activity of cytochrome c at electrified aqueous|organic interfaces

期刊

CHEMICAL COMMUNICATIONS
卷 58, 期 20, 页码 3270-3273

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc05293d

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资金

  1. Science Foundation Ireland (SFI) [13/SIRG/2137]
  2. European Research Council [716792]
  3. Irish Research Council (IRC) Government of Ireland Postdoctoral Fellowship [GOIPD/2018/252]
  4. SFI [15/CDA/3491, 12/RC/2275_P2]

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This study demonstrates that electrified aqueous|organic interfaces can be used as a suitable biomimetic platform to study and compare the accelerated electrocatalytic activity of cytochrome c in the presence of denaturing agents.
Electrochemical, spectroscopic and computational methods are used to demonstrate that electrified aqueous|organic interfaces are a suitable bio-mimetic platform to study and contrast the accelerated electrocatalytic activity of cytochrome c towards the production of reactive oxygen species (ROS) in the presence of denaturing agents such as guanidinium chloride and urea.

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