4.7 Article

Parallel-solution blow spun Al-SnO2/F-SnO2 fibers as an efficient room temperature ethanol sensor

期刊

CERAMICS INTERNATIONAL
卷 48, 期 9, 页码 13163-13174

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2022.01.193

关键词

F-doped SnO2 fibers; Al-doped SnO2 fibers; Solution blow spinning; Parallel-spinning; Ethanol sensor

资金

  1. Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - Brazil [001]
  2. National Council for Scientific and Technological Development - CNPq [308822/2018-8, 420004/2018-1]
  3. Centro Portugal Regional Operational Programme (Centro2020), under the PORTUGAL 2020Partnership Agreement, through the European Regional Development Fund (ERDF) [CEECIND/02797/2020, UIDB/00481/2020, UIDP/00481/2020, CENTRO-01-0145-FEDER022083]

向作者/读者索取更多资源

This study utilizes the Solution Blow Spinning method to fabricate Al-SnO2/F-SnO2 hybrid fibers and applies them to room-temperature ethanol sensing. The results show that the composite material exhibits high sensitivity, short response/recovery times, and good selectivity and stability. The sensing response of the composite material is 9 times higher than pure SnO2 fibers, indicating its great potential.
In the last few years, the design of room-temperature gas sensors is in growing demand. This is because high operating temperatures increase power consumption and impose unnecessary risks when working with flammable gases. This article describes the parallel-spinning fabrication of Al-SnO2/F-SnO2 hybrid fibers using the Solution Blow Spinning (SBS) method for room-temperature ethanol sensing application. The structural influence of element doping and the chemical composition/elemental states were studied by X-ray diffraction (XRD), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). The 5 at% Al-SnO2/15 at% F-SnO2 composite based sensor exhibited high sensitivity to ethanol (R = 3.0 at 100 ppm) at room temperature. This sensor also showed short response/recovery times, excellent selectivity, repeatability and long-term stability. More importantly, the sensor based on Al-SnO2/F-SnO2 composite displayed a sensing response 9 times higher than pure SnO2 fibers. These results indicate that the Al-SnO2/F-SnO2 fibers prepared in this work are promising and excellent room temperature sensing materials.

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