4.7 Article

Oxidation behaviors of compositionally complex MAX phases in air

期刊

CERAMICS INTERNATIONAL
卷 47, 期 21, 页码 30188-30193

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.07.198

关键词

Compositionally complex ceramics; MAX phases; Hot-pressing; Oxidation resistance; Ceramic composite

资金

  1. National Natural Science Foundation of China [11905194]
  2. Natural Science Foundation of Shandong

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The newly synthesized MAX phase composite containing multi-component 413 MAX phase with Ti, Nb, and Ta evenly distributed exhibits superior oxidation resistance, attributed to the formation of dense and passivating Al2O3 layers on the surface, which effectively prevents oxidation.
The oxidation behaviours of a newly synthesized MAX phase composite mainly containing a multi-component 413 MAX phase with Ti, Nb and Ta equally and evenly distributed at M site were investigated at 1000-1400 degrees C in air. Results indicated that the multi-component MAX phase exhibited superior oxidation resistance compared with traditional monolithic 413 MAX phases such as Nb4AlC3 and Ta4AlC3. Dense and passivating Al2O3 layers that formed at the interfaces between the substrate and the oxidation scale is the origin of the high oxidation resistance. The presence of Cr-Al alloy phases is essential for the formation of protective Al2O3 scale.

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