4.7 Article

VO2/ATO nanocomposite thin films with enhanced solar modulation and high luminous transmittance for smart windows

期刊

CERAMICS INTERNATIONAL
卷 48, 期 11, 页码 15868-15876

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2022.02.127

关键词

VO2/ATO composite Film ; Optical properties; High luminous transmittance

资金

  1. National Natural Science Foundation of China [51771144]
  2. Natural Science Foundation of Shaanxi Province [2019TD-020, 2021JC-06, 2019JLM30]
  3. Fundamental Scientific Research Business Expenses of Xi'a>n> Jiaotong University [xzy022020017]

向作者/读者索取更多资源

This paper develops a method to prepare high-efficiency VO2-based thin films for thermo-chromic smart windows. By preparing composites of VO2 nanoparticles and antimony-doped tin oxide (ATO) nanoparticles, the overall performances of the films are significantly boosted, achieving high luminous transmittance and large solar modulation. The optimized overall performance is achieved with a luminous transmittance of 60.14% and a solar modulation of 20%. The excellent optical properties are closely related to the dispersive small particles and widened optical band gap.
Developing an economic, facile strategy to prepare high-efficiency VO2-based thin films is critical to thermo-chromic smart windows. It is still challenging to simultaneously achieve high luminous transmittance (T-lum) and large solar modulation (delta T-sol). In this paper, the composites of VO2 nanoparticles and antimony-doped tin oxide (ATO) nanoparticles are prepared to significantly boost the overall performances of the films. As compared with pristine VO2, the T-lum value of the composite films is substantially increased from 30.91% to 84.35% by 170%, while a suitable delta T(sol & nbsp;)value of 11.57% is almost maintained. Furthermore, an optimized overall performance of T-lum (60.14%) and delta T-sol (20%) is achieved. The excellent optical properties are closely related with the dispersive small particles and widened optical band gap. The results provide an effective strategy for enhanced performances of smart windows.

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