期刊
CERAMICS INTERNATIONAL
卷 47, 期 21, 页码 29941-29948出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.07.168
关键词
Porous carbon; MnO; Supercapacitor; Heteroatom doping; Yolk-shell structure
资金
- National Natural Sci-ence Foundation of China [51703192]
- 2020 Annual Thirteenth Five Year Planning Project of the Education Department of Jilin Prov-ince [JJKH20200515KJ]
- Innovation Team Project of Yanbian University (China)
- 111 Project [D18012]
Ellipsoidal porous carbons with yolk-shell structures assembled using MnO and Ganoderma lucidum spores were fabricated for energy storage systems, exhibiting excellent ion transfer capability. Surface functionalization with heteroatom doping and O2/Ar plasma treatment improved specific capacitance and charging speed. The best sample showed a specific capacitance of 568.9 F g-1 and a capacitance retention rate of 75.11% after 10000 cycles, demonstrating potential for high-performance supercapacitors.
Owing to the significance and requirement of renewable energy resources, in this study, ellipsoidal porous carbons with yolk-shell structures assembled using MnO and Ganoderma lucidum spores are fabricated for application prospects in energy storage systems; they exhibit excellent ion transfer capability. However, the surface of carbon nanomaterials is naturally hydrophobic, resulting in a lower energy density. Herein, heteroatom doping and O2/Ar plasma surface treatment are utilized to obtain high specific capacitance and fast charging. Surface functionalization increases the surface roughness and oxygen-containing functional groups of the material. The specific capacitance of the best sample MnO/GSC-O-NS-10 was 568.9 F g-1 when the current density was 0.5 A g-1. The performance test was carried out for 10000 cycles at a current density of 10 A g-1 and the capacitance retention rate was 75.11%. The assembled two-electrode capacitor exhibited a specific capacitance of 240.4 F g-1 and an energy density of 33.4 Wh kg- 1 at a power density of 407 W kg -1. These findings provide sufficient theoretical guidance for the development of high-performance supercapacitors.
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