4.7 Article

Deep eutectic solvent recycling to prepare high purity dissolving pulp

期刊

CELLULOSE
卷 28, 期 18, 页码 11503-11517

出版社

SPRINGER
DOI: 10.1007/s10570-021-04188-9

关键词

Lactic acid; choline chloride; Eucalyptus; Dissolving pulp

资金

  1. Fundamental Research Funds of CAF [CAFYBB2018GD002]
  2. Taishan Industrial Experts Programm [tscy20200213]

向作者/读者索取更多资源

A novel acid-based deep eutectic solvent (DES) recycling process was developed for pretreating eucalyptus wood chips to produce high-purity dissolving pulp. The extracted lignin and xylan in DES were recovered and the solvent regenerated through precipitation and evaporation, leading to a high-purity dissolving pulp with improved properties. The DES pretreatment showed promise in efficiently utilizing biomass for dissolving pulp production, highlighting its potential in the biorefinery concept.
In this work, a novel acid-based deep eutectic solvent (DES) recycling process was developed for the pretreatment of eucalyptus wood chips in the preparation of high purity dissolving pulp. It was found that a large amount of lignin and xylan in the eucalyptus wood material were extracted in the recycling treatment with lactic acid/choline chloride. The dissolved lignin and xylan in DES were recovered by precipitation in water, and the DES solvent was regenerated by removing the water through evaporation. The residual lignin and xylan in the DES pre-treated wood chips were more readily removed in the subsequent kraft cooking and bleaching processes, yielding a high-purity dissolving pulp (DES-KP). Compared with the conventional prehydrolysis kraft based dissolving pulp (PHK), the DES-KP had a higher alpha-cellulose (94.02% vs. 89.81%) and a markedly higher Fock reactivity (98.94% vs. 60.97%). In addition, the DES pretreatment was also combined with oxygen-alkali cooking and ECF bleaching process, to prepare a dissolving pulp (DES-BP) with a high pulping yield (44.40%). The DES-KP pulping process was advantageous compared with the conventional PHK process in terms of the biorefinery concept, as the total utilization rate of the biomass of the eucalyptus wood chips reached 69.74%. Therefore, the DES pretreatment is a promising process for efficient biomass utilization in dissolving pulp production.

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