4.7 Article

High-performance green electronic substrate employing flexible and transparent cellulose films

期刊

CARBOHYDRATE POLYMERS
卷 270, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2021.118359

关键词

Cellulose; Dual crosslinking networks; Calendering; Maleic anhydride; Electronic substrates

资金

  1. National Key Research and Development Program of China [2018YFB1106700]
  2. General Program of National Natural Science Foundation of China [52075196, 51675199]
  3. Fundamental Research Funds for the Central Universities [2016YXZD059]

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The study presents an effective method for fabricating recyclable and high-performance cellulose films as green electronic substrates. The cellulose film exhibits high strength, improved elongation, and outstanding thermal stability, and has been successfully used as a substrate for a biomass sensor.
Today's widely used and rapidly updated electronic substrates are composed of petroleum-based polymers, but the resulting electronic waste (such as Dioxin, oxole, PCBs, etc.) will cause massive harm to the environment and human body. Therefore, we report an effective approach for fabricating recyclable and high-performance cellulose films as green electronic substrates by calendering. The crosslinking between -CH and -CH--CH- in cellulose modified by maleic anhydride led to the in-situ formation of a chemical crosslinking network, and hydrogen bonds acted as a sacrificial physical crosslinking network. The dual crosslinked cellulose film exhibits high strength (120.56 MPa), improved elongation (increased by 263%), and outstanding thermal stability (thermal decomposition temperature is 311 degrees C). Further, the film has been successfully used as a substrate for biomass sensor and realized apparent responses to changes. The scientific strategy paves the way for the largescale fabrication of high-performance cellulose films and simultaneously promotes green electronic substrates' industrialization.

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