期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 95, 期 2, 页码 230-260出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20210324
关键词
Prussian blue/Prussian blue analogues; Derivative materials; Metallic compounds
资金
- National Natural Science Foundation of China [U1904215]
- Natural Science Foundation of Jiangsu Province [BK20200044]
- Changjiang scholars program of the Ministry of Education [Q2018270]
- Guangdong-Hong Kong-Macao Joint Laboratory [2019B121205001]
This review summarizes the current progress of metallic nanomaterials derived from PB/PBA, highlighting their advantages and limitations in catalysis, as well as their applications as electrode materials for energy storage and conversion.
Prussian blue (PB) and its analogues (PBAs) are promising coordination polymers (CPs) with an adjustable composition and open framework. Nonetheless, their intrinsic electrochemical activity and electrical conductivity are poor, which hinder their applications in energy conversion and storage. In catalytic applications, metal compounds derived from PB/PBAs have a lot of advantages, such as outstanding stability, selectivity, and electrical conductivity. Furthermore, they can be used as electrode materials for electrochemical energy storage and conversion, while having preferable electronic conductivity, sufficient catalytic active sites, as well as a larger specific surface area and tunable size to achieve an optimized performance. This review summarizes the current achievements of PB/PBA-derived metallic nanomaterials, as well as the existing limitations, urgent challenges and future development.
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