The potential of Co3O4 nanoparticles attached to the surface of MnO2 nanorods as cathode catalyst for single-chamber microbial fuel cell

A simple two-step hydrothermal method was used to prepare the cathode catalyst of microbial fuel cell (MFC). MnO2@Co3O4 composite was successfully prepared by in-situ growth of nano-particle-like Co3O4 on nano-rodlike MnO2. The hybrid products had (121), (310), (311), (400) and (511) crystal planes, rod-like and pointlike structures were observed. MnO2@Co3O4 nanohybrids were rich in a variety of metallic elements and provided rich electrochemically active sites. The maximum voltage of MnO2@Co3O4-MFC was 425 mV, the maximum stabilization time was 4 d. The maximum output power was 475 mW/m2, which was 2.24 times that of Co3O4-MFC (212 mW/m2) and 2.63 times of MnO2-MFC (180 mW/m2). The rod-like structure of MnO2 could effectively improve the ion flow efficiency and reduce the transfer resistance, and the point-like structure of Co3O4 can increase the specific surface area of the complex and provide more active sites.

Automated summary

A cathode catalyst of MnO2@Co3O4 nanohybrids was prepared by a simple two-step hydrothermal method, which not only contained rich metallic elements and electrochemically active sites, but also improved the performance of microbial fuel cells, such as maximum output power and stabilization time.