One-pot synthesis of Ca-based magnetic hydrochar derived from consecutive hydrothermal and pyrolysis processing of bamboo for high-performance scavenging of Pb(II) and tetracycline from water

Ca-based magnetic bamboo-derived hydrochar described as Ca-MBHC was synthesized by one-pot pyrolysis, and was applied to remediation of lead (Pb) and tetracycline (TC) polluted water. Characterizations not only attested the loading of CaCO3 and Fe-0 onto the hydrochar, but also demonstrated the magnetism of Ca-MBHC. Adsorption kinetic experiments showed that the Ca-MBHC could eliminate Pb(II) and TC during a wide range of pH, and appeared rapid uptake equilibrium within 240 and 60 min for Pb(II) and TC, severally. Adsorption isotherm experiments showed that the Ca-MBHC possessed highest adsorption of 475.58 mg/g concerning Pb(II), and heterogeneous uptake of 142.44 mg/g for TC. Furthermore, the Ca-MBHC could achieve Pb(II) binding owing to complexation, reduction, ion exchange and electrostatic attraction, whereas the TC uptake might be related to pi-pi stacking reciprocities, pore filling and hydrogen bonding. Overall, the Ca-MBHC could be viewed as an excellent adsorbent for scavenging Pb(II) and tetracycline from water.

Automated summary

Ca-based magnetic bamboo-derived hydrochar, known as Ca-MBHC, synthesized by one-pot pyrolysis, exhibited magnetism and efficient adsorption of lead and tetracycline. Adsorption kinetic and isotherm experiments demonstrated the excellent adsorption capacity of Ca-MBHC for both pollutants.