High-performance biochar derived from the residue of Chaga mushroom (Inonotus obliquus) for pollutants removal

A high-performance biochar derived from the residue of Chaga mushroom (Inonotus obliquus) was reported in this study. Inonotus obliquus residues were used to prepare biochar, and the optimal synthesis conditions were obtained by response surface methodology. The specific surface area, pore volume, and average pore size of the optimal biochar (Zn-IORBC) was 1676.78 m2/g, 1.87 cm3/g, and 3.88 nm, respectively. Methylene blue (MB) and tetracycline (TC) were selected to estimate the adsorption performance of Zn-IORBC. The adsorption process was suitable for the pseudo-second-order model and Langmuir model. Zn-IORBC could maintained a large amount of TC adsorption (the lowest value was 686.20 mg/g in mountain spring water) in different natural water. The maximum adsorption capacity of TC and MB was 947.42 and 1033.66 mg/g. The adsorption mechanism was contributed to the electrostatic attraction, hydrogen bonding, 7C-7C interactions, and pore-filling. Zn-IORBC is an effective adsorbent for high-performance pollutants removal.

Automated summary

A high-performance biochar derived from the residue of Chaga mushroom was prepared and characterized in this study. The biochar exhibited a large specific surface area and high adsorption capacity, showing efficient adsorption of pollutants in natural water. The adsorption mechanism included electrostatic attraction, hydrogen bonding, π-π interactions, and pore-filling. Overall, the biochar showed great potential as an effective adsorbent for pollutant removal.